Stabilizing Supersaturation with Extreme Grain Refinement in Spinodal Aluminum Alloys
文献类型:期刊论文
作者 | Xu, Wei1; Zhong, Yiming1,2; Li, Xiuyan1; Lu, K.1,3 |
刊名 | ADVANCED MATERIALS
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出版日期 | 2023-08-04 |
页码 | 7 |
关键词 | aluminum alloys grain boundary relaxation grain refinement Schwarz crystal structure spinodal decomposition |
ISSN号 | 0935-9648 |
DOI | 10.1002/adma.202303650 |
通讯作者 | Li, Xiuyan(xyli@imr.ac.cn) ; Lu, K.(lu@imr.ac.cn) |
英文摘要 | Supersaturated solid solutions can be formed in alloys from various non-equilibrium processes, but stabilizing the metastable phases against decomposition is challenging, particularly the spinodal decomposition that occurs via chemical fluctuations without energy barriers to nucleation. In this work, it is found that spinodal decomposition in supersaturated Al(Zn) solid solutions can be inhibited with straining-induced extreme grain refinement. For the refined supersaturated grains at the nanoscale, their spinodal decomposition is obviously resisted by the relaxed grain boundaries and reduced lattice defects. As grains are refined below 10 nm the decomposition is completely inhibited, in which atomic diffusion is blocked by the stable Schwarz crystal structure with vacancy-free grains. Extreme grain refinement offers a general approach to stabilize supersaturated phases with broadened compositional windows for property modulation of alloys. |
资助项目 | Ministry of Science and Technology of China[2017YFA0700700] ; National Natural Science Foundation of China[52101161] ; National Natural Science Foundation of China[52225102] ; Young Elite Scientists Sponsorship Program by CAST[2022QNRC001] |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
语种 | 英语 |
WOS记录号 | WOS:001040543800001 |
出版者 | WILEY-V C H VERLAG GMBH |
资助机构 | Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Young Elite Scientists Sponsorship Program by CAST |
源URL | [http://ir.imr.ac.cn/handle/321006/178768] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Li, Xiuyan; Lu, K. |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Liaoning Acad Mat, Shenyang 110004, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Wei,Zhong, Yiming,Li, Xiuyan,et al. Stabilizing Supersaturation with Extreme Grain Refinement in Spinodal Aluminum Alloys[J]. ADVANCED MATERIALS,2023:7. |
APA | Xu, Wei,Zhong, Yiming,Li, Xiuyan,&Lu, K..(2023).Stabilizing Supersaturation with Extreme Grain Refinement in Spinodal Aluminum Alloys.ADVANCED MATERIALS,7. |
MLA | Xu, Wei,et al."Stabilizing Supersaturation with Extreme Grain Refinement in Spinodal Aluminum Alloys".ADVANCED MATERIALS (2023):7. |
入库方式: OAI收割
来源:金属研究所
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