Boosted Z-scheme photocatalytic overall water splitting with faceted Bi4TaO8Cl crystals as water oxidation photocatalyst
文献类型：期刊论文
| 作者 | Chang, Shufang5,6; Shi, Li4; Yu, Jinxing1,6; Wang, Ran1,6; Xu, Xiaoxiang1,6; Liu, Gang2,3 |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2023-07-05 |
| 卷号 | 328页码:11 |
| 关键词 | Facet -engineering Water oxidation Photocatalysis Bi4TaO8Cl Z-scheme |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2023.122541 |
| 通讯作者 | Xu, Xiaoxiang(xxxu@tongji.edu.cn) ; Liu, Gang(gangliu@imr.ac.cn) |
| 英文摘要 | We have identified a facet-assisted mechanism for photocarrier separation in flux-treated Bi4TaO8Cl crystals that expose mainly {001} and {110} facets. These two crystal facets have different energy states that provide an internal electric field to split photocarriers towards different crystal facets. We have further leveraged the phenomenon by facet-selective deposition of CoOx cocatalyst at {001} crystal facets where holes are accumulated to expedite interfacial charge transfer reactions. The coupling of these two facet-engineering techniques brings exquisite control over the flow of photocarriers which cascade continuously from bulk to the surface for catalytic reactions. Under optimal conditions, the CoOx-deposited Bi4TaO8Cl achieves an unprecedentedly high apparent quantum efficiency of 27% at 420 & PLUSMN; 20 nm for water oxidation into O2. Stable overall water splitting into H2 and O2 (molar ratio 2:1) under visible light irradiation has also been realized in a Z-scheme system employing the CoOx-deposited Bi4TaO8Cl as the O2-evolution moiety. |
| 资助项目 | National Natural Science Foundation of China[52172225] ; National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[22203046] ; National Natural Science Foundation of China[19DZ2271500] ; Science and Tech- nology Commission of Shanghai Municipality[22YF1447900] ; Shanghai Sailing Program[2021YFA1500800] ; Fundamental Research Funds for the Central Universities ; National Key R amp; D Program of China ; [51972233] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001053435900001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Science and Tech- nology Commission of Shanghai Municipality ; Shanghai Sailing Program ; Fundamental Research Funds for the Central Universities ; National Key R amp; D Program of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/178921]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xu, Xiaoxiang; Liu, Gang |
| 作者单位 | 1.Tongji Univ, Sch Chem Sci & Engn, Shanghai Key Lab Chem Assessment & Sustainabil, Shanghai 200092, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Nanjing Univ Posts & Telecommun, Displays & Inst Adv Mat, Sch Mat Sci & Engn, Jiangsu Key Lab Organ Elect & Informat, Nanjing 210023, Peoples R China 5.Shanghai Inst Technol, Sch Mat Sci & Engn, Shanghai 201418, Peoples R China 6.Tongji Univ, Putuo Peoples Hosp, Clin & Cent Lab, Shanghai 200060, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chang, Shufang,Shi, Li,Yu, Jinxing,et al. Boosted Z-scheme photocatalytic overall water splitting with faceted Bi4TaO8Cl crystals as water oxidation photocatalyst[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2023,328:11. |
| APA | Chang, Shufang,Shi, Li,Yu, Jinxing,Wang, Ran,Xu, Xiaoxiang,&Liu, Gang.(2023).Boosted Z-scheme photocatalytic overall water splitting with faceted Bi4TaO8Cl crystals as water oxidation photocatalyst.APPLIED CATALYSIS B-ENVIRONMENTAL,328,11. |
| MLA | Chang, Shufang,et al."Boosted Z-scheme photocatalytic overall water splitting with faceted Bi4TaO8Cl crystals as water oxidation photocatalyst".APPLIED CATALYSIS B-ENVIRONMENTAL 328(2023):11. |
入库方式： OAI收割
来源：金属研究所
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