Bifunctional Oxygen Electrocatalyst of Co4N and Nitrogen-Doped Carbon Nanowalls/Diamond for High-Performance Flexible Zinc-Air Batteries
文献类型：期刊论文
| 作者 | Zhang, Chuyan2,3; Huang, Nan1,2; Zhai, Zhaofeng2; Liu, Lusheng2; Chen, Bin1,2; Yang, Bing1,2; Jiang, Xin2,3; Yang, Nianjun4,5 |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2023-09-24 |
| 页码 | 12 |
| 关键词 | carbon nanowalls/diamond Co4N nanoparticles flexible Zinc-air batteries oxygen evolution reaction oxygen reduction reaction |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.202301749 |
| 通讯作者 | Huang, Nan(nhuang@imr.ac.cn) ; Jiang, Xin(xin.jiang@uni-siegen.de) ; Yang, Nianjun(nianjun.yang@uhasselt.be) |
| 英文摘要 | Rational design of heterogeneous catalysts with unique structural and electronic properties is one of the major challenges to improve the activity toward the reversible oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), the bottleneck in the construction of air cathodes for the next-generation flexible zinc-air batteries (ZABs). Herein, density functional theory calculations are combined with experimental attempts to exploit the roles of the electronic effects at the interface between Co4N nanoparticles and nitrogen-doped carbon nanowalls/diamond (d-NCNWs/D) toward the ORR and OER activities. The vacancy defect-induced Co-pyridinic N-C bond optimizes the electronic structure of Co 3d orbitals and balances the adsorption energies of intermediates along the reaction pathways. Consequently, as-synthesized Co4N@d-NCNWs/D composites exhibit superior bifunctional oxygen catalytic activity. The overpotential of the OER is as low as 340 mV at 10 mA cm(-2) and the high half-wave potential reaches 0.83 V for the ORR. As a binder-free and flexible ZABs cathode, this composite exhibits an open circuit voltage of 1.41 V and excellent bendable stability, proving its promising potential for the assembly of wearable devices. This work offers theoretical evidence and a controllable strategy to design high-performance ZAB cathodes for their application in smart electronic devices. |
| 资助项目 | The authors are grateful to the Shenzhen Cloud Computing Center for allowing the use of their computing facilities for DFT simulations. N.H. sincerely acknowledges financial support from the Jie Bang Gua Shuai Key Technologies R amp;amp; D Program of Li[2021JH1/10400031] ; National Natural Science Foundation of China[51202257] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001070621500001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | The authors are grateful to the Shenzhen Cloud Computing Center for allowing the use of their computing facilities for DFT simulations. N.H. sincerely acknowledges financial support from the Jie Bang Gua Shuai Key Technologies R amp;amp; D Program of Li ; National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/179307]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Huang, Nan; Jiang, Xin; Yang, Nianjun |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Univ Siegen, Inst Mat Engn, 9-11 Paul Bonatz Str, D-57076 Siegen, Germany 4.Hasselt Univ, Dept Chem, Agoralaan 1, B-3590 Diepenbeek, Belgium 5.Hasselt Univ, IMO IMOMEC, Wetenschapspk 1, B-3590 Diepenbeek, Belgium |
| 推荐引用方式 GB/T 7714 | Zhang, Chuyan,Huang, Nan,Zhai, Zhaofeng,et al. Bifunctional Oxygen Electrocatalyst of Co4N and Nitrogen-Doped Carbon Nanowalls/Diamond for High-Performance Flexible Zinc-Air Batteries[J]. ADVANCED ENERGY MATERIALS,2023:12. |
| APA | Zhang, Chuyan.,Huang, Nan.,Zhai, Zhaofeng.,Liu, Lusheng.,Chen, Bin.,...&Yang, Nianjun.(2023).Bifunctional Oxygen Electrocatalyst of Co4N and Nitrogen-Doped Carbon Nanowalls/Diamond for High-Performance Flexible Zinc-Air Batteries.ADVANCED ENERGY MATERIALS,12. |
| MLA | Zhang, Chuyan,et al."Bifunctional Oxygen Electrocatalyst of Co4N and Nitrogen-Doped Carbon Nanowalls/Diamond for High-Performance Flexible Zinc-Air Batteries".ADVANCED ENERGY MATERIALS (2023):12. |
入库方式： OAI收割
来源：金属研究所
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