Electron confinement promoted the electric double layer effect of BiOI/ B-Bi2O3 in photocatalytic water splitting
文献类型：期刊论文
| 作者 | Shan, Lianwei4; Fang, Zilan4; Ding, Guodao4; Shi, Ziqi4; Dong, Limin4; Li, Dan4; Wu, Haitao1; Li, Xuejiao4; Suriyaprakash, Jagadeesh3; Zhou, Yangtao2 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2024 |
| 卷号 | 653页码:94-107 |
| 关键词 | Confinement Photocatalysis S-scheme heterojunction Electric double layer |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2023.09.059 |
| 通讯作者 | Dong, Limin(donglimin@hrbust.edu.cn) ; Wu, Haitao(wuhaitao@ytu.edu.cn) ; Suriyaprakash, Jagadeesh(jaga@m.scnu.edu.cn) |
| 英文摘要 | In the realm of photocatalysis, understanding the interface issues (solid/solid and solid/liquid) inherent in heterojunction at the atomic level is the ultimate for engineering an efficient photocatalyst. Herein, an electrophoretic deposition technique is adopted to synthesize BiOI/B-Bi2O3 heterojunction, exhibiting superior photocatalytic activity and stability in H2 evolution (91.5 mu mol g-1 h-1) and H2O2 production (11.3 mg L-1 h-1). Combined with the experimental and computational results, a lower free energy of hydrogen evolution reaction (252.4 meV) has been observed contrast to BiOI and B-Bi2O3 samples. A carrier transfer process of like S-scheme heterojunction is proposed based on density of states (DOS) and carrier distribution calculations. The theoretical calculations illustrate the transition dipole moment, migration and accumulation of carrier in BiOI/B-Bi2O3 heterojunction. Subsequent ab initio molecular dynamics (AIMD) results of solid/liquid interface systems (BiOI/ B-Bi2O3/H2O and B-Bi2O3/H2O) unravel the interface H2O (solvent) behaviors. The local aggregation of photo generated electrons in BiOI/B-Bi2O3/H2O leads to a large potential drop, high proton migration rate and the steady electric double layer (EDL) structure compared to the B-Bi2O3/H2O, which facilitates the occurrence of photocatalytic reactions in solution. In addition to offering new insights into the hydrogen evolution and proton transfer in the EDL model and the association between the heterojunction effect and EDL structure, this work also introduces a novel design strategy for Bi-based heterojunctions. |
| 资助项目 | Nature Scientific Foundation of Heilongjiang Province[ZD2022E005] ; Ecological and Environmental Protection Research Project of Heilongjiang Province[HST2022S010] ; China Postdoctoral Science Foundation[2020M672669] ; Natural Science Foundation of Shandong Province[ZR2021LSW014] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001076887800001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Nature Scientific Foundation of Heilongjiang Province ; Ecological and Environmental Protection Research Project of Heilongjiang Province ; China Postdoctoral Science Foundation ; Natural Science Foundation of Shandong Province |
| 源URL | [http://ir.imr.ac.cn/handle/321006/179370]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Dong, Limin; Wu, Haitao; Suriyaprakash, Jagadeesh |
| 作者单位 | 1.Yantai Univ, Sch Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China 3.South China Normal Univ, Sch Informat & Optoelect Sci & Engn, Guangdong Prov Key Lab Nanophoton Funct Mat & Dev, Guangzhou 510006, Peoples R China 4.Harbin Univ Sci & Technol, Sch Mat Sci & Chem Engn, Heilongjiang Prov Key Lab CO Resource Utilizat & E, Harbin 150040, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shan, Lianwei,Fang, Zilan,Ding, Guodao,et al. Electron confinement promoted the electric double layer effect of BiOI/ B-Bi2O3 in photocatalytic water splitting[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2024,653:94-107. |
| APA | Shan, Lianwei.,Fang, Zilan.,Ding, Guodao.,Shi, Ziqi.,Dong, Limin.,...&Xiao, Yanwei.(2024).Electron confinement promoted the electric double layer effect of BiOI/ B-Bi2O3 in photocatalytic water splitting.JOURNAL OF COLLOID AND INTERFACE SCIENCE,653,94-107. |
| MLA | Shan, Lianwei,et al."Electron confinement promoted the electric double layer effect of BiOI/ B-Bi2O3 in photocatalytic water splitting".JOURNAL OF COLLOID AND INTERFACE SCIENCE 653(2024):94-107. |
入库方式： OAI收割
来源：金属研究所
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