Antimony-Coated Carbon Nanocomposites as High-Performance Anode Materials for High-Temperature Sodium-Metal Batteries
文献类型：期刊论文
| 作者 | Iqbal, Sundas1; Ma, Yue1; Wei, Bingqing3; Ali, Mustehsin2; Zhao, Tingkai1 |
| 刊名 | ACS APPLIED NANO MATERIALS
 |
| 出版日期 | 2023-09-22 |
| 卷号 | 6期号:19页码:18247-18254 |
| 关键词 | sodium-metal anode plating/stripping dendrite-free sodiophilic antimony-coated carbon(Sb@C) nanocomposites |
| DOI | 10.1021/acsanm.3c03486 |
| 通讯作者 | Ma, Yue(mayue04@nwpu.edu.cn) ; Zhao, Tingkai(ztk@nwpu.edu.cn) |
| 英文摘要 | Metallic sodium (Na) possesses several advantageous characteristics, including a high theoretical specific capacity, low electrode potential, and availability in abundance, making it an ideal anode material for sodium-metal batteries (SMBs). However, the practical use of Na metal anodes is severely impeded due to the uncontrolled formation of dendrites due to the slow electrochemical kinetics and chemical instability of the formed solid-electrolyte interphase (SEI) layer. This situation can worsen considerably under high-temperature (HT) conditions (>55 degrees C). To overcome this issue, we have fabricated a thermally stable antimony (Sb)-coated carbon (Sb@C) nanocomposite as a sodium host material, where Sb nanoparticles are encapsulated within the carbon layers. This unique nanostructure controls vaporization during the plating-stripping process and dendrite formation and provides acceptor sites for Na+ ions. The Sb@C electrode exhibits an extended life span of symmetrical cycles (2400 h at 1 mA cm(-2)) due to the abundant nucleation sites. It maintains a low nucleation overpotential (similar to 15 mV), enhancing its performance and long cycle stability. Moreover, the in situ formed Na-Sb synergistically offers durable ionic/electronic diffusion paths and chemically interacts with Na, forming abundant Na nucleation sites. Therefore, in this study, we emphasize the importance of the rational design of highly stable alloys and present an effective strategy for achieving high-performance sodium-metal anodes. |
| 资助项目 | National Natural Science Foundation of China[51872231] ; National Natural Science Foundation of China[51672221] ; Key Industrial Chain Project of Shaanxi Province, China[2018ZDCXL-GY-08-07] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001071369300001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Key Industrial Chain Project of Shaanxi Province, China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/179448]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Ma, Yue; Zhao, Tingkai |
| 作者单位 | 1.Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Peoples R China 2.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China 3.Univ Delaware, Mech Engn, Newark, DE 19716 USA |
| 推荐引用方式 GB/T 7714 | Iqbal, Sundas,Ma, Yue,Wei, Bingqing,et al. Antimony-Coated Carbon Nanocomposites as High-Performance Anode Materials for High-Temperature Sodium-Metal Batteries[J]. ACS APPLIED NANO MATERIALS,2023,6(19):18247-18254. |
| APA | Iqbal, Sundas,Ma, Yue,Wei, Bingqing,Ali, Mustehsin,&Zhao, Tingkai.(2023).Antimony-Coated Carbon Nanocomposites as High-Performance Anode Materials for High-Temperature Sodium-Metal Batteries.ACS APPLIED NANO MATERIALS,6(19),18247-18254. |
| MLA | Iqbal, Sundas,et al."Antimony-Coated Carbon Nanocomposites as High-Performance Anode Materials for High-Temperature Sodium-Metal Batteries".ACS APPLIED NANO MATERIALS 6.19(2023):18247-18254. |
入库方式： OAI收割
来源：金属研究所
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