Formation mechanism of Gulong shale oil: Insights from semiclosed hydrous pyrolysis
文献类型：期刊论文
| 作者 | Zhang, Yuchen1,4; Bai, Xuefeng2; Wang, Min1,4; Li, Junhui2; Zhang, Jinyou2; Fu, Li2; Huo, Qiuli2; Li, Jinbu3; Yan, Yu1,4; Xu, Liang2 |
| 刊名 | JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
 |
| 出版日期 | 2024-08-01 |
| 卷号 | 181页码:12 |
| 关键词 | Hydrocarbon generation Semiclosed system Hydrous pyrolysis Qingshankou Formation Shale oil |
| ISSN号 | 0165-2370 |
| DOI | 10.1016/j.jaap.2024.106632 |
| 英文摘要 | As a typical lacustrine shale oil, Gulong shale oil has enormous resource potential. The current lack of understanding regarding the formation process of this oil has affected its development. This study uses a low-mature shale sample from the first member of the Qingshankou Formation in the Songliao Basin and analyzes the hydrocarbon generation, expulsion, and retention characteristics by conducting hydrous pyrolysis in a semiclosed system. The results show that the formation process of the Gulong shale oil can be divided into three stages. The slow hydrocarbon generation stage occurs when organic matter maturity (Ro) < 0.8 %, and only a small amount of hydrocarbons is generated by kerogen cracking. The products are mainly heavy components (C15+), with retained oil composing the majority of them. The rapid oil generation stage occurs when Ro is of 0.8 %-1.1 %, where a large amount of kerogen is cracked to generate hydrocarbons and reaches its peak when Ro is 1.1 %. Most of generated light component oil (C-6-C-14) is expelled, and retained oil is mostly composed of heavy components (C15+); Ro > 1.1 % indicates the stage of oil cracking and rapid gas generation. Light component oil (C-6-C-14) and gaseous hydrocarbons (C-1-C-5) are formed when heavy components oil (C15+) begins to crack. The light-to-heavy ratio of the hydrocarbon products (C-1-C-14/C15+) rapidly increases with maturity. The hydrous pyrolysis experiment in a semiclosed system is more in line with actual geological conditions of Qingshankou Formation compared to other experimental systems and can simultaneously consider the influence of geological factors such as temperature, pressure, hydrocarbon expulsion, and formation water. |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001272853100001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/72354]  |
| 专题 | 中国科学院广州地球化学研究所 |
| 通讯作者 | Wang, Min |
| 作者单位 | 1.China Univ Petr East China, Natl Key Lab Deep Oil & Gas, Qingdao 266580, Peoples R China 2.PetroChina Daqing Oilfield Co, Explorat & Dev Res Inst, Daqing 163712, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 4.China Univ Petr East China, Sch Geosci, Qingdao 266580, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yuchen,Bai, Xuefeng,Wang, Min,et al. Formation mechanism of Gulong shale oil: Insights from semiclosed hydrous pyrolysis[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2024,181:12. |
| APA | Zhang, Yuchen.,Bai, Xuefeng.,Wang, Min.,Li, Junhui.,Zhang, Jinyou.,...&Wu, Yan.(2024).Formation mechanism of Gulong shale oil: Insights from semiclosed hydrous pyrolysis.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,181,12. |
| MLA | Zhang, Yuchen,et al."Formation mechanism of Gulong shale oil: Insights from semiclosed hydrous pyrolysis".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 181(2024):12. |
入库方式： OAI收割
来源：广州地球化学研究所
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