Quantitative evaluation model of shale oil adsorption: A case study of the first member of Cretaceous Qingshankou Formation in northern Songliao Basin, NE China
文献类型:期刊论文
作者 | Li, Jinbu3,4; Wang, Min4; Lu, Shuangfang2; Liu, Liang4; Li, Ming4; Zhang, Yuchen4; Wang, Xin4; Zhao, Xinbin4; Zhang, Jinyou1; Zhao, Ying1 |
刊名 | PETROLEUM EXPLORATION AND DEVELOPMENT
![]() |
出版日期 | 2023-10-01 |
卷号 | 50期号:5页码:1137-1150 |
关键词 | shale oil adsorbed oil occurrence state mobility Cretaceous Qingshankou Formation Evaluation model Songliao Basin |
ISSN号 | 2096-4803 |
DOI | 10.1016/S1876-3804(23)60454-9 |
英文摘要 | A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed, and the evaluation charts of adsorption-swelling capacity of kerogen (M-k) and adsorbed oil capacity of clay minerals (Mc) were established, taking the 1st member of Cretaceous Qingshankou Formation in the northern Songliao Basin as an example. The model and charts were derived from swelling oil experiments performed on naturally evolved kerogens and adsorbed oil experiments on clays (separated from shale core samples). They were constructed on the basis of clarifying the control law of kerogen maturity evolution on its adsorption-swelling capacity, and considering the effect of both the clay pore surface area that occupied by adsorbed oil and formation temperature. The results are obtained in four aspects: (1) For the Qing 1 Member shale, with the increase of maturity, M-k decreases. Given R-o of 0.83%-1.65%, M-k is about 50-250 mg/g. (2) The clay in shale adsorbs asphaltene. Mc is 0.63 mg/m2, and about 15% of the clay pore surface is occupied by adsorbed oil. (3) In the low to medium maturity stages, the shale oil adsorption is controlled by organic matter. When R-o>1.3%, the shale oil adsorption capacity is contributed by clay pores. (4) The oil adsorption capacity evaluated on the surface at room temperature is 8%-22% (avg. 15%) higher than that is held in the formations. The proposed evaluation model reveals the occurrence mechanisms of shale oils with different maturities, and provides a new insight for estimating the reserves of shale oil under formation temperature conditions. |
WOS研究方向 | Energy & Fuels ; Engineering ; Geology |
语种 | 英语 |
WOS记录号 | WOS:001093223400001 |
源URL | [http://ir.gig.ac.cn/handle/344008/78760] ![]() |
专题 | 中国科学院广州地球化学研究所 |
通讯作者 | Wang, Min |
作者单位 | 1.PetroChina Daqing Oilfield Co, Explorat & Dev Res Inst, Daqing 163712, Peoples R China 2.Northeast Petr Univ, Sanya Offshore Oil & Gas Res Inst, Sanya 572025, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 4.China Univ Petr East China, Natl Key Lab Deep Oil & Gas, Qingdao 266580, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jinbu,Wang, Min,Lu, Shuangfang,et al. Quantitative evaluation model of shale oil adsorption: A case study of the first member of Cretaceous Qingshankou Formation in northern Songliao Basin, NE China[J]. PETROLEUM EXPLORATION AND DEVELOPMENT,2023,50(5):1137-1150. |
APA | Li, Jinbu.,Wang, Min.,Lu, Shuangfang.,Liu, Liang.,Li, Ming.,...&Zhao, Ying.(2023).Quantitative evaluation model of shale oil adsorption: A case study of the first member of Cretaceous Qingshankou Formation in northern Songliao Basin, NE China.PETROLEUM EXPLORATION AND DEVELOPMENT,50(5),1137-1150. |
MLA | Li, Jinbu,et al."Quantitative evaluation model of shale oil adsorption: A case study of the first member of Cretaceous Qingshankou Formation in northern Songliao Basin, NE China".PETROLEUM EXPLORATION AND DEVELOPMENT 50.5(2023):1137-1150. |
入库方式: OAI收割
来源:广州地球化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。