中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Transition metal Carbides/Nitrides (MXenes): Properties, synthesis, functional modification and photocatalytic application

文献类型:期刊论文

作者Li, Ning3; Huo, Jianlin3; Zhang, Yue3; Ye, Bin4; Chen, Xiaojuan3; Li, Xiaofei3; Xu, Song3; He, Juhua3; Chen, Xin3; Tang, Yuntong3
刊名SEPARATION AND PURIFICATION TECHNOLOGY
出版日期2024-02-01
卷号330页码:39
关键词MXenes Etching methods Functional modification Photocatalysis
ISSN号1383-5866
DOI10.1016/j.seppur.2023.125325
英文摘要As a new metal carbides/nitrides material, MXenes behaves unique crystal and electronic structure, showing the advantages of metal-like conductivity, prominent optical properties, flexible adjustability of elemental composition, rich surface chemical activity, and regular layered structure. Hence, this review firstly provides a detailed investigation of the structural and optical characteristics of MXenes to determine its feasibility as photocatalysts. Then, the preparation methods of MXenes are summarized, among which the etching methods are the most commonly used, mainly including fluorine-containing solution etching, alkali solution etching, electrochemical etching, and molten salt etching etc. Different preparation methods can obtain MXenes with differentiated structural morphologies and photocatalytic activity. However, the poor oxidation stability of MXenes during photocatalytic reactions conducted in aqueous media remains a challenging issue. Excitedly, MXenes with abundant suspended bonds on its surfaces are also easily functionalized. Therefore, the next section is a systematical summary of the functional modification strategies of MXenes, and after modification with organic, inorganic, organic-inorganic hybrid, or ion intercalation, MXenes can exhibit various properties and superior stability in aqueous solutions, further enhancing its photocatalytic adaptability. Based on these points, the review also systematically discusses the application progress of MXenes-based materials in photocatalysis, including degradation of organic pollutants, hydrogen evolution via the decomposition of water, carbon dioxide reduction, nitrogen fixation, reduction and removal of heavy metals, as well as sterilization and disinfection. Overall, the introduction of MXenes into photocatalysts provides rich photogenerated electron transfer channels and promotes the efficient separation of photogenerated carriers, thereby improving the photocatalytic oxidation or reduction reactions. Lastly, the development outlook of MXenes-based materials is also prospected.
WOS研究方向Engineering
语种英语
WOS记录号WOS:001098346800001
源URL[http://ir.gig.ac.cn/handle/344008/78937]  
专题中国科学院广州地球化学研究所
通讯作者Chen, Xiaojuan; Zhu, Runliang
作者单位1.South China Agr Univ, Coll Nat Resources & Environm, Guangzhou 510642, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China
3.Foshan Univ, Sch Environm & Chem Engn, Foshan 528000, Peoples R China
4.Minist Ecol & Environm Peoples Republ China, Appraisal Ctr Environm & Engn, Beijing 100012, Peoples R China
推荐引用方式
GB/T 7714
Li, Ning,Huo, Jianlin,Zhang, Yue,et al. Transition metal Carbides/Nitrides (MXenes): Properties, synthesis, functional modification and photocatalytic application[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2024,330:39.
APA Li, Ning.,Huo, Jianlin.,Zhang, Yue.,Ye, Bin.,Chen, Xiaojuan.,...&Zhu, Runliang.(2024).Transition metal Carbides/Nitrides (MXenes): Properties, synthesis, functional modification and photocatalytic application.SEPARATION AND PURIFICATION TECHNOLOGY,330,39.
MLA Li, Ning,et al."Transition metal Carbides/Nitrides (MXenes): Properties, synthesis, functional modification and photocatalytic application".SEPARATION AND PURIFICATION TECHNOLOGY 330(2024):39.

入库方式: OAI收割

来源:广州地球化学研究所

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