Resin composition: An indicator of oil maturity as revealed by fourier transform ion cyclotron resonance mass spectrometry
文献类型：期刊论文
| 作者 | Liang, Tian1,2,3; Zhan, Zhao -Wen1,3; Wang, Guo-Xiang1,2,3; Zou, Yan-Rong1,3 |
| 刊名 | PETROLEUM SCIENCE
 |
| 出版日期 | 2023-04-01 |
| 卷号 | 20期号:2页码:769-775 |
| 关键词 | Resin Pyrolysis FT-ICR MS Heteroatom compound Maturity DBE |
| ISSN号 | 1672-5107 |
| DOI | 10.1016/j.petsci.2022.09.014 |
| 英文摘要 | A pyrolysis experiment was carried out on a Dongying Depression kerogen sample to separate the resin from the oil. Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) with a positive -ion detector was used to detect the relative proportional changes in the compounds of the resin. During the whole pyrolysis experiment, the relative ratio of resin exceed 10% of the soluble component at each temperature point. Five compounds were detected from the resin: N1, N1O1, N1O2, O1, and O2. To research the changes in the proportions of the compounds during pyrolysis clearly, these five compounds were divided into three classes: N1, N1Ox, and Ox. The N1 class has the largest proportion in resin at the beginning of the pyrolysis, while Ox class has the least proportion. And the relationship between the number and the molecular mass of three classes compound was researched. With increasing maturity, the proportion of N1 and the N1Ox class decreased rapidly, while the Ox class increased slowly. Through researching these resin compounds, it was found that an inversion in the proportions of above three compounds appeared at the end of the oil window. At the same time, we found that the DBE and carbon number of resin compounds have changed obviously during the pyrolysis: the DBE increased, while the carbon number decreased significantly. And the details of the change of each compound have been researched. This research extends our knowledge of judging the maturity of crude oil during the py-rolysis through the characteristics of compounds in resin and provides the new index based on resin for the evaluation of thermal evolution stage and hydrocarbon generation capacity of source rocks.(c) 2023 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/). |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000994761000001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/74273]  |
| 专题 | 有机地球化学国家重点实验室 |
| 通讯作者 | Zou, Yan-Rong |
| 作者单位 | 1.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Tian,Zhan, Zhao -Wen,Wang, Guo-Xiang,et al. Resin composition: An indicator of oil maturity as revealed by fourier transform ion cyclotron resonance mass spectrometry[J]. PETROLEUM SCIENCE,2023,20(2):769-775. |
| APA | Liang, Tian,Zhan, Zhao -Wen,Wang, Guo-Xiang,&Zou, Yan-Rong.(2023).Resin composition: An indicator of oil maturity as revealed by fourier transform ion cyclotron resonance mass spectrometry.PETROLEUM SCIENCE,20(2),769-775. |
| MLA | Liang, Tian,et al."Resin composition: An indicator of oil maturity as revealed by fourier transform ion cyclotron resonance mass spectrometry".PETROLEUM SCIENCE 20.2(2023):769-775. |
入库方式： OAI收割
来源：广州地球化学研究所
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