Nitroaromatic Compounds from Secondary Nitrate Formation and Biomass Burning Are Major Proinflammatory Components in Organic Aerosols in Guangzhou: A Bioassay Combining High-Resolution Mass Spectrometry Analysis
文献类型：期刊论文
| 作者 | Zhang, Qianyu5,6,7; Ma, Huimin6,7; Li, Jun6,7; Jiang, Hongxing6,7; Chen, Wenjing5,6,7; Wan, Cong6,7; Jiang, Bin6,7; Dong, Guanghui4; Zeng, Xiaowen4; Chen, Duohong3,6 |
| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2023-11-21 |
| 卷号 | 57期号:51页码:21570-21580 |
| 关键词 | PM2.5 organicaerosols inflammation screening FT-ICR-MS source environmentalprocess |
| ISSN号 | 0013-936X |
| DOI | 10.1021/acs.est.3c04983 |
| 英文摘要 | The limited characterization and detection capacity of unknown compounds hinder our understanding of the molecular composition of toxic compounds in PM2.5. The present study applied Fourier transform ion cyclotron resonance mass spectrometry coupled with negative and positive electrospray ionization sources (ESI-/ESI+ FT-ICR-MS) to probe the molecular characteristics and dynamic formation processes of the effective proinflammatory components in organic aerosols (OAs) of PM2.5 in Guangzhou for one year. We detected abundant proinflammatory molecules in OAs, mainly classified as CHON compounds (compounds composed of C, H, O, and N atoms) in elemental and nitroaromatic compounds (NACs) in structures. From the perspective of the formation process, we discovered that these proinflammatory molecules, especially toxic NACs, were largely driven by secondary nitrate formation and biomass burning (in emission source), as well as SO2 (in atmospheric evolution). In addition, our results indicated that the secondary processes had replaced the primary emission as the main contributing source of the toxic proinflammatory compounds in OAs. This study highlights the importance of community measures to control the production of nitroaromatic compounds derived from secondary nitrate formation and biomass burning in urban areas. |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001132972200001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/76051]  |
| 专题 | 有机地球化学国家重点实验室 |
| 通讯作者 | Ma, Huimin; Li, Jun |
| 作者单位 | 1.Sun Yat Sen Univ, Sch Publ Hlth Shenzhen, Shenzhen 518107, Peoples R China 2.Jinan Univ, Sch Environm, Guangdong Key Lab Environm Pollut & Hlth, Guangzhou 511443, Peoples R China 3.Guangdong Environm Monitoring Ctr, Dept Air Qual Forecasting & Early Warning, State Environm Protect Key Lab Reg Air Qual Monito, Guangdong Environm Protect Key Lab Atmospher Secon, Guangzhou 510308, Peoples R China 4.Sun Yat Sen Univ, Sch Publ Hlth, Dept Prevent Med, Guangzhou 510080, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 6.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Environm Protect & Resource, Guangzhou 510640, Peoples R China 7.Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Qianyu,Ma, Huimin,Li, Jun,et al. Nitroaromatic Compounds from Secondary Nitrate Formation and Biomass Burning Are Major Proinflammatory Components in Organic Aerosols in Guangzhou: A Bioassay Combining High-Resolution Mass Spectrometry Analysis[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2023,57(51):21570-21580. |
| APA | Zhang, Qianyu.,Ma, Huimin.,Li, Jun.,Jiang, Hongxing.,Chen, Wenjing.,...&Zhang, Gan.(2023).Nitroaromatic Compounds from Secondary Nitrate Formation and Biomass Burning Are Major Proinflammatory Components in Organic Aerosols in Guangzhou: A Bioassay Combining High-Resolution Mass Spectrometry Analysis.ENVIRONMENTAL SCIENCE & TECHNOLOGY,57(51),21570-21580. |
| MLA | Zhang, Qianyu,et al."Nitroaromatic Compounds from Secondary Nitrate Formation and Biomass Burning Are Major Proinflammatory Components in Organic Aerosols in Guangzhou: A Bioassay Combining High-Resolution Mass Spectrometry Analysis".ENVIRONMENTAL SCIENCE & TECHNOLOGY 57.51(2023):21570-21580. |
入库方式： OAI收割
来源：广州地球化学研究所
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