Application of an absolute reference frame for methane clumped-isotope analyses
文献类型：期刊论文
| 作者 | Liu, Qingmei3,4,6; Li, Jiacheng3,4,6; Jiang, Wenmin4,6; Li, Yun4,6 ; Lin, Mang2,4; Liu, Wen3,4,6; Shuai, Yanhua1; Zhang, Haizu5; Peng, Ping'an4,6; Xiong, Yongqiang4,6
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| 刊名 | CHEMICAL GEOLOGY
 |
| 出版日期 | 2024-02-20 |
| 卷号 | 646页码:9 |
| 关键词 | Methane Clumped isotopes High-resolution gas-source isotope-ratio mass spectrometry Absolute reference frame Formation temperature |
| ISSN号 | 0009-2541 |
| DOI | 10.1016/j.chemgeo.2024.121922 |
| 英文摘要 | Clumped-isotope analysis provides new constraints on the formation and evolution of methane. High-resolution isotope-ratio mass spectrometry (HR-IRMS) is a sensitive, precise, and stable analytical technique increasingly used in methane clumped-isotope analysis. However, the lack of standard reference frames hinders the comparison of data from different laboratories and the evaluation of accuracy. In this study, an absolute reference frame was introduced for HR-IRMS analysis of the multiply substituted methane isotopologues (CH3D)-C-13 and (CH2D2)-C-12. We evaluated the optimized performance of a Panorama (Nu Instruments, UK) HR-IRMS system by repeated analysis of an intra-laboratory standard gas, finding that these rare isotopologues can be analyzed separately with high precision, repeatability, and reproducibility. Internal precision (a key parameter in instrument performance) reached 0.15 parts per thousand - 0.25 parts per thousand for Delta(CH3D)-C-13 and 0.70 parts per thousand - 0.85 parts per thousand for Delta(CH2D2)-C-12 values, ensuring the reliability of data. Comparison of results before and after purification demonstrated that purification procedures caused negligible isotopic fractionation of clumped isotopes. Isotopic-exchange experiments revealed source effects in the MS ion source, depending on the difference in bulk H isotopic composition between sample and reference gas, but independent of bulk C isotopic composition. To improve analytical accuracy for methane isotopologues, an absolute reference frame was developed through experiments involving a suite of mixed gases of different H isotopic composition equilibrated at 100 degrees C and a standard gas equilibrated at 2 degrees C-500 degrees C. Based on the reference frame, raw data were processed with a non-linearity correction and converted to real values with empirical transformation functions. The reference frame was applied to analyses of two methane standard gases and three natural gases from Tarim Basin, China. Measured Delta(CH3D)-C-13 and Delta(CH2D2)-C-12 values for two standard gases were consistent with published values. Clumped-isotope signatures of natural gases preserve information related to the formation temperature of methane. |
| WOS研究方向 | Geochemistry & Geophysics |
| 语种 | 英语 |
| WOS记录号 | WOS:001156367000001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/76218]  |
| 专题 | 有机地球化学国家重点实验室 |
| 通讯作者 | Xiong, Yongqiang |
| 作者单位 | 1.Petrochina Res Inst Petr Explorat & Dev, Beijing, Peoples R China 2.Chinese Acad Sci, State Key Lab Isotope Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China 5.Petrochina Tarim Oilfield Co, Kuerle 841000, Peoples R China 6.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Qingmei,Li, Jiacheng,Jiang, Wenmin,et al. Application of an absolute reference frame for methane clumped-isotope analyses[J]. CHEMICAL GEOLOGY,2024,646:9. |
| APA | Liu, Qingmei.,Li, Jiacheng.,Jiang, Wenmin.,Li, Yun.,Lin, Mang.,...&Xiong, Yongqiang.(2024).Application of an absolute reference frame for methane clumped-isotope analyses.CHEMICAL GEOLOGY,646,9. |
| MLA | Liu, Qingmei,et al."Application of an absolute reference frame for methane clumped-isotope analyses".CHEMICAL GEOLOGY 646(2024):9. |
入库方式： OAI收割
来源：广州地球化学研究所
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