Clay minerals inhibit the release of Cd(II) during the phase transformation of Cd(II)-ferrihydrite coprecipitates
文献类型:期刊论文
作者 | Han, Bin1,2,3; Liu, Jing4; Zhu, Runliang1,2,3![]() |
刊名 | JOURNAL OF HAZARDOUS MATERIALS
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出版日期 | 2024-01-15 |
卷号 | 462页码:13 |
关键词 | Ferrihydrite Clay minerals Phase transformation Heavy metals Immobilization |
ISSN号 | 0304-3894 |
DOI | 10.1016/j.jhazmat.2023.132723 |
英文摘要 | Clay minerals and iron (hydr)oxides are important geosorbents in controlling the migration of heavy metal cations in the environment. Despite the widespread occurrence of clay minerals/iron (hydr)oxides composites, their complex mutual effects on the fate of heavy metal cations are not well recognized. In this work, we investigated the effect of clay minerals on the redistribution of Cd(II) during the phase transformation of ferrihydrite containing coprecipitated Cd(II) (Cd-Fh). Three systems were considered: i.e., Cd-Fh, Cd-Fh/kaolinite composite, and Cd-Fh/montmorillonite composite. Our results showed that the transformation of Fh into goethite and hematite caused the release of Cd(II), while the presence of kaolinite and montmorillonite inhibited the phase transformation of Fh and the release of Cd(II), with montmorillonite being more effective in these process. Multiple factors contributed to the reduced release of Cd(II), including the retarded transformation of Fh, the buffering of solution pH, and the re-adsorption of the released Cd(II). Our findings show that clay minerals have multiple effects in reducing the release of heavy metal cations from Fh during its transformation |
WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
语种 | 英语 |
WOS记录号 | WOS:001099171300001 |
源URL | [http://ir.gig.ac.cn/handle/344008/78971] ![]() |
专题 | 有机地球化学国家重点实验室 |
通讯作者 | Liu, Jing; Chen, Qingze |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 4.Macau Univ Sci & Technol, State Key Lab Lunar & Planetary Sci, Taipa 999078, Macau, Peoples R China |
推荐引用方式 GB/T 7714 | Han, Bin,Liu, Jing,Zhu, Runliang,et al. Clay minerals inhibit the release of Cd(II) during the phase transformation of Cd(II)-ferrihydrite coprecipitates[J]. JOURNAL OF HAZARDOUS MATERIALS,2024,462:13. |
APA | Han, Bin,Liu, Jing,Zhu, Runliang,&Chen, Qingze.(2024).Clay minerals inhibit the release of Cd(II) during the phase transformation of Cd(II)-ferrihydrite coprecipitates.JOURNAL OF HAZARDOUS MATERIALS,462,13. |
MLA | Han, Bin,et al."Clay minerals inhibit the release of Cd(II) during the phase transformation of Cd(II)-ferrihydrite coprecipitates".JOURNAL OF HAZARDOUS MATERIALS 462(2024):13. |
入库方式: OAI收割
来源:广州地球化学研究所
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