Oxidation state of Cu in silicate melts at upper mantle conditions
文献类型：期刊论文
| 作者 | Liu, Xingcheng1,2; Zhang, Lei1,2; Zhu, Sanyuan3; Li, Li1; Xiong, Xiaolin1,2 |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2024-03-09 |
| 卷号 | 14期号:1页码:9 |
| ISSN号 | 2045-2322 |
| DOI | 10.1038/s41598-024-56538-9 |
| 英文摘要 | Beyond its economic value, copper (Cu) serves as a valuable tracer of deep magmatic processes due to its close relationship with magmatic sulfide evolution and sensitivity to oxygen fugacity (fO2). However, determining Cu's oxidation state (+ 1 or + 2) in silicate melts, crucial for interpreting its behavior and reconstructing fO2 in the Earth's interior, has long been a challenge. This study utilizes X-ray Absorption Near Edge Structure spectroscopy to investigate the Cu oxidation state in hydrous mafic silicate melts equilibrated under diverse fO2 (- 1.8 to 3.1 log units relative to the Fayalite-Magnetite-Quartz buffer), temperature (1150-1300 degrees C), and pressure (1.0-2.5 GPa) conditions. Our results reveal that Cu predominantly exists as Cu+ across all fO2 conditions, with a minor Cu2+ component. This dominance of Cu+ persists even in relatively oxidized melts, highlighting its limited sensitivity to fO2 under upper mantle conditions. This significantly constrains the utility of Cu as an oxybarometer in hydrous silicate melts in the deep Earth. However, our findings suggest that Cu isotopes primarily reflect the interplay of sulfide segregation/accumulation during magmatic differentiation, shedding light on these fundamental processes in Earth's interior. |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:001185505600003 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/77181]  |
| 专题 | 同位素地球化学国家重点实验室 |
| 通讯作者 | Liu, Xingcheng; Zhu, Sanyuan |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Isotope Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xingcheng,Zhang, Lei,Zhu, Sanyuan,et al. Oxidation state of Cu in silicate melts at upper mantle conditions[J]. SCIENTIFIC REPORTS,2024,14(1):9. |
| APA | Liu, Xingcheng,Zhang, Lei,Zhu, Sanyuan,Li, Li,&Xiong, Xiaolin.(2024).Oxidation state of Cu in silicate melts at upper mantle conditions.SCIENTIFIC REPORTS,14(1),9. |
| MLA | Liu, Xingcheng,et al."Oxidation state of Cu in silicate melts at upper mantle conditions".SCIENTIFIC REPORTS 14.1(2024):9. |
入库方式： OAI收割
来源：广州地球化学研究所
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