Ion exchange of glass under high pressure
文献类型：期刊论文
| 作者 | Xu, Yanan1; Liu, Shuang1; Ding, Linfeng1; Li, Jianfeng2; Song, Maoshuang2; Wang, Lianjun1 |
| 刊名 | SCRIPTA MATERIALIA
 |
| 出版日期 | 2024-10-01 |
| 卷号 | 251页码:5 |
| 关键词 | Oxide glass High pressure Ion exchange Chemical strengthening Activation volume |
| ISSN号 | 1359-6462 |
| DOI | 10.1016/j.scriptamat.2024.116221 |
| 英文摘要 | Ion exchange is a pivotal method for enhancing the mechanical properties of oxide glasses, yet the influence of pressure on this process and its underlying mechanisms are not fully elucidated. This investigation pioneers the successful implementation of high-pressure ion exchange in commercial lithium aluminosilicate glass using Paterson press, achieving pressures above 100 MPa. Our findings unveil that moderate pressures promote ion interdiffusion, while extreme pressures hinder it due to glass network densification, which restricts ion mobility. Activation energy for ion exchange notably increases from 85.8 +/- 0.7 kJ/mol at ambient pressure to 93.2 +/- 4.6 kJ/mol at 50 MPa, highlighting the significant role of pressure on ion exchange kinetics. The large activation volume (similar to 146 cm(3)/mol) associated with the process underscores the extensive volume alterations involved in ion exchange. These insights underscore the potential of high-pressure processing in improving the mechanical properties of glass. |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001257361000001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/78321]  |
| 专题 | 同位素地球化学国家重点实验室 |
| 通讯作者 | Ding, Linfeng; Li, Jianfeng |
| 作者单位 | 1.Donghua Univ, Engn Res Ctr Adv Glass Mfg Technol, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ, Shanghai 201620, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Isotope Geochem, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Yanan,Liu, Shuang,Ding, Linfeng,et al. Ion exchange of glass under high pressure[J]. SCRIPTA MATERIALIA,2024,251:5. |
| APA | Xu, Yanan,Liu, Shuang,Ding, Linfeng,Li, Jianfeng,Song, Maoshuang,&Wang, Lianjun.(2024).Ion exchange of glass under high pressure.SCRIPTA MATERIALIA,251,5. |
| MLA | Xu, Yanan,et al."Ion exchange of glass under high pressure".SCRIPTA MATERIALIA 251(2024):5. |
入库方式： OAI收割
来源：广州地球化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。