Complexation of REE in Hydrothermal Fluids and Its Significance on REE Mineralization
文献类型：期刊论文
| 作者 | Di, Jian1,2,3; Ding, Xing1,2,3 |
| 刊名 | MINERALS
 |
| 出版日期 | 2024-06-01 |
| 卷号 | 14期号:6页码:26 |
| 关键词 | rare earth elements REE complexation speciation REE complex hydrothermal fluids |
| DOI | 10.3390/min14060531 |
| 英文摘要 | Rare earth elements (REEs) have recently been classified as critical and strategic metals due to their importance in modern society. Research on the geochemical behaviors and mineralization of REEs not only provides essential guidance for mineral exploration but also holds great significance in enhancing our understanding of Earth's origin and evolution. This paper reviews recent research on the occurrence characteristics, deposit types, and hydrothermal behaviors of REEs, with a particular focus on comparing the complexation and transport of REEs by F, Cl, S, C, P, OH, and organic ligands in fluids. Due to the very weak hydrolysis of REE ions, they predominantly exist as either hydrated ions or free ions in low-temperature and acidic to weakly basic fluids. As the ligand activity increases, the general order of transporting REEs is Cl- approximate to SO42- > F- approximate to PO43-- > CO32- > OH- under acidic conditions or OH- > SO42- approximate to Cl- > F- under alkaline conditions. In acidic to neutral hydrothermal systems, the transport of REEs is primarily dominated by SO42- and Cl- ions while the deposition of REEs could be influenced by F-, CO32-, and PO43- ions. In neutral to alkaline hydrothermal systems, REEs mainly exist in fluids as hydroxyl complexes or other ligand-bearing hydroxyl complexes. Additionally suggested are further comprehensive investigations that will fill significant gaps in our understanding of mechanisms governing the transport and enrichment of REEs in hydrothermal fluids. |
| WOS研究方向 | Geochemistry & Geophysics ; Mineralogy ; Mining & Mineral Processing |
| 语种 | 英语 |
| WOS记录号 | WOS:001257651100001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/78330]  |
| 专题 | 同位素地球化学国家重点实验室 |
| 通讯作者 | Ding, Xing |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Isotope Geochem, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100101, Peoples R China 3.Guangzhou Inst Geochem, CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Di, Jian,Ding, Xing. Complexation of REE in Hydrothermal Fluids and Its Significance on REE Mineralization[J]. MINERALS,2024,14(6):26. |
| APA | Di, Jian,&Ding, Xing.(2024).Complexation of REE in Hydrothermal Fluids and Its Significance on REE Mineralization.MINERALS,14(6),26. |
| MLA | Di, Jian,et al."Complexation of REE in Hydrothermal Fluids and Its Significance on REE Mineralization".MINERALS 14.6(2024):26. |
入库方式： OAI收割
来源：广州地球化学研究所
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