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Chinese Academy of Sciences Institutional Repositories Grid
Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam

文献类型:期刊论文

作者Wang, Christina Yan1,4,5; Bai, Yuying2,4,5; Wei, Bo1,4,5; Minh, Dinh Huu3
刊名JOURNAL OF ASIAN EARTH SCIENCES
出版日期2023-10-01
卷号255页码:16
关键词Cobaltite-gersdorffite solid solution (CGss) Platinum-group elements (PGE) Ban Phuc Ni-Cu-(PGE) sulfide deposit Northern Vietnam
ISSN号1367-9120
DOI10.1016/j.jseaes.2023.105781
英文摘要The Ban Phuc Ni-Cu-(PGE) sulfide deposit in northern Vietnam contains no or few platinum-group minerals (PGM) in massive sulfide ores, and most PGM grains occur in altered disseminated sulfide ores, including sperrylite (PtAs2), irarsite-orarsite-hollingworthite [IrAsS, OsAsS, (Rh,Ir)AsS], and froodite-sobolevskitesudburyite [PdBi2, PdBi, Pd(SbBi) and PdSb]. Discrete PGM grains are enclosed within serpentines and base metal sulfides (BMS) of the disseminated ores. In contrast, small amounts (0.004 vol%) of cobaltite-gersdorffite solid solution (CGss) in massive sulfide ores commonly contain high PGE concentrations relative to the BMS. Textural relationships reveal that the CGss grains crystallize earlier than the host BMS in massive sulfide ores. The CGss grains are found to contain all six PGE and act as the major hosts for the PGE in the massive sulfide ores. The fast Fourier transform (FFT) patterns of high resolution TEM images show that the irarsite (IrAsS) enclosed within the CGss shares the same zone axis of (2 1 2), which results from the exsolution of irarsite from the CGss. On the other hand, the CGss grains without visible PGM show an even distribution of PGE in the crystal and respective FFT patterns of CGss crystals. This is an example of a growing number of cases that massive sulfide ores have been found to contain PGE in As-bearing minerals, either PGM including sperrylite and members of the irarsite-orarsite-hollingworthite solid solution series or CGss. These results argue that PGE in the sulfide melt may enter the CGss at high temperature before the crystallization of monosulfide solution, rather than soluble in BMS, even if the sulfide melt was not As-saturated.
WOS研究方向Geology
语种英语
WOS记录号WOS:001033875000001
源URL[http://ir.gig.ac.cn/handle/344008/74583]  
专题中国科学院矿物学与成矿学重点实验室
通讯作者Wang, Christina Yan
作者单位1.Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
3.Asian Mineral Resources, Hanoi, Vietnam
4.Chinese Acad Sci, Guangzhou Inst Geochem, Key Lab Mineral & Metallogeny, Guangzhou 510640, Peoples R China
5.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China
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Wang, Christina Yan,Bai, Yuying,Wei, Bo,et al. Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam[J]. JOURNAL OF ASIAN EARTH SCIENCES,2023,255:16.
APA Wang, Christina Yan,Bai, Yuying,Wei, Bo,&Minh, Dinh Huu.(2023).Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam.JOURNAL OF ASIAN EARTH SCIENCES,255,16.
MLA Wang, Christina Yan,et al."Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam".JOURNAL OF ASIAN EARTH SCIENCES 255(2023):16.

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来源:广州地球化学研究所

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