Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam
文献类型:期刊论文
作者 | Wang, Christina Yan1,4,5; Bai, Yuying2,4,5; Wei, Bo1,4,5; Minh, Dinh Huu3 |
刊名 | JOURNAL OF ASIAN EARTH SCIENCES
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出版日期 | 2023-10-01 |
卷号 | 255页码:16 |
关键词 | Cobaltite-gersdorffite solid solution (CGss) Platinum-group elements (PGE) Ban Phuc Ni-Cu-(PGE) sulfide deposit Northern Vietnam |
ISSN号 | 1367-9120 |
DOI | 10.1016/j.jseaes.2023.105781 |
英文摘要 | The Ban Phuc Ni-Cu-(PGE) sulfide deposit in northern Vietnam contains no or few platinum-group minerals (PGM) in massive sulfide ores, and most PGM grains occur in altered disseminated sulfide ores, including sperrylite (PtAs2), irarsite-orarsite-hollingworthite [IrAsS, OsAsS, (Rh,Ir)AsS], and froodite-sobolevskitesudburyite [PdBi2, PdBi, Pd(SbBi) and PdSb]. Discrete PGM grains are enclosed within serpentines and base metal sulfides (BMS) of the disseminated ores. In contrast, small amounts (0.004 vol%) of cobaltite-gersdorffite solid solution (CGss) in massive sulfide ores commonly contain high PGE concentrations relative to the BMS. Textural relationships reveal that the CGss grains crystallize earlier than the host BMS in massive sulfide ores. The CGss grains are found to contain all six PGE and act as the major hosts for the PGE in the massive sulfide ores. The fast Fourier transform (FFT) patterns of high resolution TEM images show that the irarsite (IrAsS) enclosed within the CGss shares the same zone axis of (2 1 2), which results from the exsolution of irarsite from the CGss. On the other hand, the CGss grains without visible PGM show an even distribution of PGE in the crystal and respective FFT patterns of CGss crystals. This is an example of a growing number of cases that massive sulfide ores have been found to contain PGE in As-bearing minerals, either PGM including sperrylite and members of the irarsite-orarsite-hollingworthite solid solution series or CGss. These results argue that PGE in the sulfide melt may enter the CGss at high temperature before the crystallization of monosulfide solution, rather than soluble in BMS, even if the sulfide melt was not As-saturated. |
WOS研究方向 | Geology |
语种 | 英语 |
WOS记录号 | WOS:001033875000001 |
源URL | [http://ir.gig.ac.cn/handle/344008/74583] ![]() |
专题 | 中国科学院矿物学与成矿学重点实验室 |
通讯作者 | Wang, Christina Yan |
作者单位 | 1.Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Asian Mineral Resources, Hanoi, Vietnam 4.Chinese Acad Sci, Guangzhou Inst Geochem, Key Lab Mineral & Metallogeny, Guangzhou 510640, Peoples R China 5.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Christina Yan,Bai, Yuying,Wei, Bo,et al. Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam[J]. JOURNAL OF ASIAN EARTH SCIENCES,2023,255:16. |
APA | Wang, Christina Yan,Bai, Yuying,Wei, Bo,&Minh, Dinh Huu.(2023).Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam.JOURNAL OF ASIAN EARTH SCIENCES,255,16. |
MLA | Wang, Christina Yan,et al."Cobaltite-gersdorffite solid solution as a collector of platinum-group elements in the Ban Phuc Ni-Cu-(PGE) sulfide deposit, northern Vietnam".JOURNAL OF ASIAN EARTH SCIENCES 255(2023):16. |
入库方式: OAI收割
来源:广州地球化学研究所
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