Construction of an allophane-based molecularly imprinted polymer for the efficient removal of antibiotic from aqueous solution
文献类型：期刊论文
| 作者 | Ma, Qiyi2,3,4; Wei, Yanfu5; Zhao, Ning2,3,4; Wang, Shun1,3; Zhang, Baifa2; Liu, Dong3,4 ; Yuan, Peng2,3
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| 刊名 | SCIENCE OF THE TOTAL ENVIRONMENT
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| 出版日期 | 2023-12-10 |
| 卷号 | 903页码:11 |
| 关键词 | Molecularly imprinted polymers Allophane Adsorption Ciprofloxacin |
| ISSN号 | 0048-9697 |
| DOI | 10.1016/j.scitotenv.2023.166464 |
| 英文摘要 | The widespread presence of ciprofloxacin (CIP) antibiotic in the water and soil poses substantial potential risks to the environment, threatening both human and animal health. In this study, we used nanoclay mineral allophane (Allo), ll-cyclodextrin (ll-CD) as a bifunctional monomer, and sodium alginate as a cross-linking agent, to prepare 3D porous Allo-ll-CD molecularly imprinted polymers (MIPs) for the efficient removal of CIP from aqueous solution. The prepared Allo-ll-CD MIP was characterized by scanning electron microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and zeta potential measurements. The effects of initial concentration, time, pH level, and ion concentration on CIP removal dynamics were systematically studied. The adsorption kinetics and equilibrium data of CIP were well-fitted by the pseudo-second-order kinetic model and Langmuir isotherm models, respectively. The Allo-ll-CD MIP can efficiently remove CIP from an aqueous solution, with a maximal adsorption capacity of 635 mg/g. It also has impressive recyclability, and enhanced selectivity, and is widely adaptable to various environmental conditions. The adsorption mechanisms of the as-prepared adsorbent include H bonds, hydrophobic interactions, surface complexation, and n-pi EDA interactions. Given the experimental evidence, as-prepared adsorbent is therefore a promising candidate for the effective removal of CIP from the aquatic environment. |
| WOS研究方向 | Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001075626900001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/74878]  |
| 专题 | 中国科学院矿物学与成矿学重点实验室 |
| 通讯作者 | Yuan, Peng |
| 作者单位 | 1.Songshan Lake Mat Lab, Neutron Sci Platform, Dongguan 523808, Peoples R China 2.Guangdong Univ Technol, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Macau Univ Sci & Technol, Macao Environm Res Inst, Natl Observat & Res Stn Coastal Ecol Environm Maca, Macau 999078, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Qiyi,Wei, Yanfu,Zhao, Ning,et al. Construction of an allophane-based molecularly imprinted polymer for the efficient removal of antibiotic from aqueous solution[J]. SCIENCE OF THE TOTAL ENVIRONMENT,2023,903:11. |
| APA | Ma, Qiyi.,Wei, Yanfu.,Zhao, Ning.,Wang, Shun.,Zhang, Baifa.,...&Yuan, Peng.(2023).Construction of an allophane-based molecularly imprinted polymer for the efficient removal of antibiotic from aqueous solution.SCIENCE OF THE TOTAL ENVIRONMENT,903,11. |
| MLA | Ma, Qiyi,et al."Construction of an allophane-based molecularly imprinted polymer for the efficient removal of antibiotic from aqueous solution".SCIENCE OF THE TOTAL ENVIRONMENT 903(2023):11. |
入库方式： OAI收割
来源：广州地球化学研究所
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