V2O5 modified Mn/SAPO-34 catalyst for the synchronous elimination of NOx and volatile organic compounds
文献类型：期刊论文
| 作者 | Xiong, Tao1,4; Xiao, Gaofei4; Lin, Beilong4; Li, Qitian4; Fu, Mingli2,3,4; Hu, Yun2,3,4 |
| 刊名 | CATALYSIS TODAY
 |
| 出版日期 | 2024-03-15 |
| 卷号 | 430页码:12 |
| 关键词 | VOCs Catalytic oxidation NOx reduction Synchronous elimination Hierarchical pores |
| ISSN号 | 0920-5861 |
| DOI | 10.1016/j.cattod.2024.114535 |
| 英文摘要 | In this work, a new V-Mn bimetallic multifunctional catalyst based on SAPO-34 zeolite was constructed to achieve synchronous elimination of VOCs and NOx in denitrification zone conditions. The V-Mn/SAPO-34 catalyst exhibited excellent catalytic performance for toluene oxidation and NO reduction and remarkable flue gas tolerance compared to Mn/SAPO-34 and V/SAPO-34. The T90 (265 C) of V-Mn/SAPO-34 for toluene oxidation was 30 C and 125 C lower than that of Mn/SAPO-34 (295 C) and V/SAPO-34, respectively. Moreover, the conversion of NO could reach more than 90% at 138 C. Excellent catalytic activity of the V-Mn/ SAPO-34 was attributed to abundant hierarchical pores, oxygen vacancies and acidic sites owing to ion exchanges of SAPO-34. Meanwhile, the favorable V-Mn synergy effectively facilitated the electron transfer of catalytic reaction. In situ DRIFTS results indicated that the toluene oxidation over it followed the MvK mechanism, while the NH3-SCR followed the E -R mechanism, and the two, proceeding independently, did not interfere with each other during synchronous elimination. |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001176426800001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/77260]  |
| 专题 | 中国科学院矿物学与成矿学重点实验室 |
| 通讯作者 | Hu, Yun |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 2.Guangdong Prov Engn & Technol Res Ctr Environm Ris, Guangzhou 510006, Peoples R China 3.Guangdong Prov Key Lab Atmospher Environm & Pollut, Guangzhou 510006, Peoples R China 4.South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Tao,Xiao, Gaofei,Lin, Beilong,et al. V2O5 modified Mn/SAPO-34 catalyst for the synchronous elimination of NOx and volatile organic compounds[J]. CATALYSIS TODAY,2024,430:12. |
| APA | Xiong, Tao,Xiao, Gaofei,Lin, Beilong,Li, Qitian,Fu, Mingli,&Hu, Yun.(2024).V2O5 modified Mn/SAPO-34 catalyst for the synchronous elimination of NOx and volatile organic compounds.CATALYSIS TODAY,430,12. |
| MLA | Xiong, Tao,et al."V2O5 modified Mn/SAPO-34 catalyst for the synchronous elimination of NOx and volatile organic compounds".CATALYSIS TODAY 430(2024):12. |
入库方式： OAI收割
来源：广州地球化学研究所
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