Improving the flame retardancy and smoke suppression of ethylene vinyl acetate composites by introducing the hybrid material of Zn/TiO2@AKaol
文献类型：期刊论文
| 作者 | Tang, Wufei2,3; Zhang, Huimin1; Liu, Ting3; Li, Xinle3; Yang, Hua3; Huang, Weizhen3; Liao, Yunhui3; Gu, Xiaoyu1; Zhang, Sheng1 |
| 刊名 | POLYMER DEGRADATION AND STABILITY
 |
| 出版日期 | 2024-03-01 |
| 卷号 | 221页码:11 |
| 关键词 | Flame retardancy Smoke suppression Kaolinite Ethylene vinyl acetate copolymer Mechanism |
| ISSN号 | 0141-3910 |
| DOI | 10.1016/j.polymdegradstab.2024.110673 |
| 英文摘要 | Ethylene vinyl acetate copolymer (EVA) is widely applied in many important fields, but its broader utility is impeded by its flammability. To address this problem, the pre-acidified kaolinite (AKaol) by sulfuric acid was further dealt with TiO2 loading and Zn2+ doping to obtain Zn/TiO2@AKaol to improve the flame retardancy and smoke suppression of EVA composites containing intumescent flame retardants (IFR) typically. The results showed that the addition of 1 wt% Zn/TiO2@AKaol improved the flame retardancy and reduced the smoke release of EVA/IFR composite. The limiting oxygen index (LOI) value of the EVA/IFR composite containing Zn/ TiO2@AKaol increased to 32.7 % from 27.3 % of EVA/IFR composite. In the cone calorimeter test (CCT), the peak heat release rate (pHRR) and total heat release (THR) values were reduced to 297.5 kW/m2 and 98.8 MJ/ m2 from the 409.9 kW/m2 and 109.3 MJ/m2 of EVA/IFR composite, respectively. Meanwhile, the values of total smoke production (TSP) in the CCT and smoke density tests in building materials were reduced to 13.5 m2 and 33.39 % of EVA/IFR/Zn/TiO2@AKaol composite from 18.4 m2 and 63.91 % of EVA/IFR composite, respectively. Based on the mechanism analysis, it was proposed that Zn/TiO2@AKaol not only promoted the production of P & sdot; in advance, but also increased a cross-linked structure char in the condensed phase to achieve flame retardancy and smoke suppression of EVA composites. |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001179082400001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/77273]  |
| 专题 | 中国科学院矿物学与成矿学重点实验室 |
| 通讯作者 | Tang, Wufei; Gu, Xiaoyu |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 3.Hunan Univ Sci & Engn, Coll Chem & Bioengn, Hunan Engn Technol Res Ctr Comprehens Dev & Utiliz, Yongzhou 425199, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Wufei,Zhang, Huimin,Liu, Ting,et al. Improving the flame retardancy and smoke suppression of ethylene vinyl acetate composites by introducing the hybrid material of Zn/TiO2@AKaol[J]. POLYMER DEGRADATION AND STABILITY,2024,221:11. |
| APA | Tang, Wufei.,Zhang, Huimin.,Liu, Ting.,Li, Xinle.,Yang, Hua.,...&Zhang, Sheng.(2024).Improving the flame retardancy and smoke suppression of ethylene vinyl acetate composites by introducing the hybrid material of Zn/TiO2@AKaol.POLYMER DEGRADATION AND STABILITY,221,11. |
| MLA | Tang, Wufei,et al."Improving the flame retardancy and smoke suppression of ethylene vinyl acetate composites by introducing the hybrid material of Zn/TiO2@AKaol".POLYMER DEGRADATION AND STABILITY 221(2024):11. |
入库方式： OAI收割
来源：广州地球化学研究所
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