Directional self-assembly of octavinyl polyhedral oligomeric silsesquioxane on the surface of melamine sponge: Establishing hydrophobic surfaces to improve oil-water separation performance
文献类型:期刊论文
作者 | Chen, Jing7; Zhang, Xiaokang7; Zhang, Li1; Jiang, Xiangzhan6; Xiao, Fei4,5; Hu, Jinghui1,2,3,6; Ding, Jiawang2,3 |
刊名 | JOURNAL OF MOLECULAR LIQUIDS
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出版日期 | 2024-06-15 |
卷号 | 404页码:12 |
关键词 | Melamine sponge Octavinyl POSS Oil -water separation Superhydrophobic Flame retardant |
ISSN号 | 0167-7322 |
DOI | 10.1016/j.molliq.2024.124941 |
通讯作者 | Hu, Jinghui(bykfhjh@163.com) |
英文摘要 | The continuous increase in industrial organic pollutants has seriously contaminated the natural environment, posing a threat to natural ecosystems and human survival. The preparation of hydrophobic materials with corrosion resistance is crucial for the efficient treatment of emulsified oil-water mixtures in industrial wastewater. Octavinyl polyhedral oligomeric silsesquioxane-coated melamine foam (OV-POSS@MF), possessing hydrophobic properties, was synthesized through a two-step process: initially, a sulfhydryl layer was built up on the surface of the melamine foam, followed by the subsequent assembly of octavinyl POSS onto the melamine foam's surface via a free radical polymerization reaction between sulfhydryl groups and vinyl moieties. OV-POSS@MF achieves a static water contact angle of 141 degrees, demonstrating its pronounced hydrophobic nature. Moreover, the corrosion resistance, adsorption capacity, oil-water separation efficiency, deformation resistance, and flame retardancy of OV-POSS@MF were thoroughly examined. The results indicate that OV-POSS@MF exhibits strong corrosion resistance and maintains good hydrophobicity even after prolonged exposure to highly acidic and alkaline conditions. Notably, OV-POSS@MF possesses the capability to efficiently and rapidly separate emulsified oil-water mixtures. Furthermore, it retains excellent hydrophobicity even after undergoing up to 100 consecutive compressions or distortions, highlighting its remarkable mechanical resilience. Additionally, OVPOSS@MF demonstrates superior flame retardant properties compared to unmodified melamine foam (MF). |
WOS关键词 | SUPERHYDROPHOBIC COATINGS ; FABRICATION ; HYBRID ; MESHES ; FOAM |
资助项目 | National Natural Science Foundation of China[NSFC 82102209] ; Shandong Provincial Natural Science Foundation Youth Fund[ZR2022QE230] ; Scientific Foundation of Binzhou Medical University, China[BY2019KYQD47] ; Scientific Foundation of Binzhou Medical University, China[50012304494] ; Scientific Foundation of Binzhou Medical University, China[50012304488] ; Scientific Foundation of Binzhou Medical University, China[KQRH2024ZD003] ; Scientific Foundation of Binzhou Medical University, China[KQRH2024MS002] ; Yantai School-City Integration Development Project -Digital Stomatology Innovation Research platform[2023XDRHXMPT11] |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
WOS记录号 | WOS:001241980900001 |
出版者 | ELSEVIER |
源URL | [http://ir.qdio.ac.cn/handle/337002/186032] ![]() |
专题 | 中国科学院海洋研究所 |
通讯作者 | Hu, Jinghui |
作者单位 | 1.Binzhou Med Univ, Inst Stomatol, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 4.North Univ China, Safety Engn, Taiyuan 030051, Shanxi, Peoples R China 5.North Univ China, Sch Environm, Taiyuan 030051, Shanxi, Peoples R China 6.Binzhou Med Univ, Sch Special Educ & Rehabil, Yantai 264003, Peoples R China 7.Binzhou Med Univ, Sch Pharm, Key Lab Prescript Effect, Clin Evaluat State Adm Tradit Chinese Med China, Yantai 264003, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Jing,Zhang, Xiaokang,Zhang, Li,et al. Directional self-assembly of octavinyl polyhedral oligomeric silsesquioxane on the surface of melamine sponge: Establishing hydrophobic surfaces to improve oil-water separation performance[J]. JOURNAL OF MOLECULAR LIQUIDS,2024,404:12. |
APA | Chen, Jing.,Zhang, Xiaokang.,Zhang, Li.,Jiang, Xiangzhan.,Xiao, Fei.,...&Ding, Jiawang.(2024).Directional self-assembly of octavinyl polyhedral oligomeric silsesquioxane on the surface of melamine sponge: Establishing hydrophobic surfaces to improve oil-water separation performance.JOURNAL OF MOLECULAR LIQUIDS,404,12. |
MLA | Chen, Jing,et al."Directional self-assembly of octavinyl polyhedral oligomeric silsesquioxane on the surface of melamine sponge: Establishing hydrophobic surfaces to improve oil-water separation performance".JOURNAL OF MOLECULAR LIQUIDS 404(2024):12. |
入库方式: OAI收割
来源:海洋研究所
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