Engineering a hard sol-gel adaptive coating with nonleaching antifoulant against marine biofouling in static conditions
文献类型:期刊论文
作者 | Sun, Yihan2; Shen, Yuanyuan2; Zhao, Haibin2; Wang, Peng2![]() |
刊名 | PROGRESS IN ORGANIC COATINGS
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出版日期 | 2024-06-01 |
卷号 | 191页码:9 |
关键词 | Antifouling Fouling release Biofouling Low surface energy Coating |
ISSN号 | 0300-9440 |
DOI | 10.1016/j.porgcoat.2024.108402 |
通讯作者 | Wang, Peng(wangpeng@qdio.ac.cn) |
英文摘要 | Covalently tethered, nonleaching antifoulant groups to surface or coating matrix are being explored as an ecofriendly option to develop a robust antifouling coating with enhanced static antifouling ability. And most of marine antifouling coatings usually have a relatively low coating hardness owing to intrinsically polymeric property. In this work, we exploited the self-assembly of random zwitterionic amphiphilic copolymers with an isothiazolinone-based antifoulant to develop a scalable hard (> 6H pencil hardness) coating against marine biofouling under static conditions. Upon exposure to aqueous media, strong fluorinate-zwitterion interactions drive microphase separation into bicontinuous networks of hydrophobic and zwitterionic nanodomains, leading to the enrichment of antifoulant moieties on the coating surface. The obtained hybrid coating could significantly restrain the growth of bacteria biofilms, the settlement of marine diatoms and mussel larvae owing to the presence of covalently tethered antifoulants. Oxidative stress levels in the body of bacteria and marine diatoms were significantly enhanced nearby the coating containing nonteaching antifoulants. On the other hand, the fouling release capability was not compromising on the developed hybrid coating with such high Young's modulus and large coating hardness, implying an obviously different antifouling mechanism. We attempt to report an ecofriendly and hard coating system to simultaneously prohibit fouling settlement and promote fouling removal in static conditions. |
WOS关键词 | FOULING-RELEASE COATINGS ; ADHESION ; COPOLYMERS ; BIOCIDES ; IMPACT |
资助项目 | National Natural Science Foundation of China[52205227] ; National Natural Science Foundation of China[U22A20112] ; Shandong Province Natural Science Foundation[ZR2020KE008] ; Nantong Scientific Plan Foundation[JC12022099] |
WOS研究方向 | Chemistry ; Materials Science |
语种 | 英语 |
WOS记录号 | WOS:001219080000001 |
出版者 | ELSEVIER SCIENCE SA |
源URL | [http://ir.qdio.ac.cn/handle/337002/185673] ![]() |
专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
通讯作者 | Wang, Peng |
作者单位 | 1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Yihan,Shen, Yuanyuan,Zhao, Haibin,et al. Engineering a hard sol-gel adaptive coating with nonleaching antifoulant against marine biofouling in static conditions[J]. PROGRESS IN ORGANIC COATINGS,2024,191:9. |
APA | Sun, Yihan,Shen, Yuanyuan,Zhao, Haibin,&Wang, Peng.(2024).Engineering a hard sol-gel adaptive coating with nonleaching antifoulant against marine biofouling in static conditions.PROGRESS IN ORGANIC COATINGS,191,9. |
MLA | Sun, Yihan,et al."Engineering a hard sol-gel adaptive coating with nonleaching antifoulant against marine biofouling in static conditions".PROGRESS IN ORGANIC COATINGS 191(2024):9. |
入库方式: OAI收割
来源:海洋研究所
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