Fe doping in In2S3 hollow nanotubes for efficient photo-Fenton degradation of emerging organic pollutants
文献类型：期刊论文
| 作者 | Wang, Chunli2,3; Liu, Nazhen3; Liu, Xiangju3; Jiang, Quantong3; Tian, Yong1; Xie, Haijiao4; Chen, Xuwei2; Hou, Baorong3 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2024-10-01 |
| 卷号 | 345页码:11 |
| 关键词 | Photo-Fenton reaction Fe-In2S3 microtubes Homolytic cleavage Tetracycline Wastewater treatment |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2024.127405 |
| 通讯作者 | Liu, Nazhen(liunazhen@qdio.ac.cn) ; Tian, Yong(tianyong@qut.edu.cn) |
| 英文摘要 | The primary factor in the application of heterogeneous Fenton catalysts for practical wastewater treatment lies in the effective activation of hydrogen peroxide (H2O2). Herein, a Fe-doped In2S3 hollow nanotube catalyst (FeIn2S3) is developed and optimized to enable visible light-induced H2O2 activation aimed at the efficient degradation of organic pollutants. Computational analysis indicates that Fe doping aids in the adsorption and catalytic decomposition of H2O2, facilitating homolytic cleavage and resulting in the generation of highly oxidative hydroxyl radicals (center dot OH). Moreover, Fe doping improves the light absorption capability of In2S3 and fosters the separation of photogenerated charge carriers. The ongoing production of photoexcited electrons supports the valence cycling of Fe species, maintaining elevated catalytic activity. In experiments involving tetracycline (TC) degradation with Fe-In2S3, the observed pseudo-first-order kinetic constant (k(obs)) is 5.5 times greater than that of the single Fenton reaction after visible light exposure. Within the photo-Fenton system, the kobs of Fe-In2S3 is 0.151 min(-1), which is 6.5 times greater than that of In2S3. Owing to the formation of multiple active species during the photo-Fenton catalytic processes, Fe-In2S3 demonstrates remarkable degradation efficiencies against a range of organic contaminants typically found in wastewater. |
| WOS关键词 | HYDROXYL RADICALS ; WATER |
| 资助项目 | CAS Pioneer Hundred Talents Program ; National Natural Science Foundation of China[41827805] ; Shandong Province Higher Educational Program for Introduction and Cultivation of Young Innovative Talents |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001228488100001 |
| 出版者 | ELSEVIER |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/185892]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 通讯作者 | Liu, Nazhen; Tian, Yong |
| 作者单位 | 1.Qingdao Univ Technol, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China 2.Northeastern Univ, Coll Sci, Res Ctr Analyt Sci, Dept Chem, Box 332, Shenyang 110819, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 4.Hangzhou Yanqu Informat Technol Co Ltd, Hangzhou 310003, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chunli,Liu, Nazhen,Liu, Xiangju,et al. Fe doping in In2S3 hollow nanotubes for efficient photo-Fenton degradation of emerging organic pollutants[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2024,345:11. |
| APA | Wang, Chunli.,Liu, Nazhen.,Liu, Xiangju.,Jiang, Quantong.,Tian, Yong.,...&Hou, Baorong.(2024).Fe doping in In2S3 hollow nanotubes for efficient photo-Fenton degradation of emerging organic pollutants.SEPARATION AND PURIFICATION TECHNOLOGY,345,11. |
| MLA | Wang, Chunli,et al."Fe doping in In2S3 hollow nanotubes for efficient photo-Fenton degradation of emerging organic pollutants".SEPARATION AND PURIFICATION TECHNOLOGY 345(2024):11. |
入库方式： OAI收割
来源：海洋研究所
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