Thermal Shock Synthesis for Loading Sub-2 nm Ru Nanoclusters on Titanium Nitride as a Remarkable Electrocatalyst toward Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Zong, Lingbo4; Lu, Fenghong4; Li, Ping4; Fan, Kaicai4; Zhan, Tianrong4; Liu, Porun5; Jiang, Lixue1; Chen, Dehong2; Zhang, Ruiyong3; Wang, Lei4 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2024-06-07 |
| 页码 | 9 |
| 关键词 | hydrogen evolution reaction (HER) interfacial perimeters metal-support interaction (MSI) nanoclusters thermal shock synthesis |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.202403525 |
| 通讯作者 | Wang, Lei(inorchemwl@qust.edu.cn) |
| 英文摘要 | Heterogeneous catalysts embracing metal entities on suitable supports are profound in catalyzing various chemical reactions, and substantial synthetic endeavors in metal-support interaction modulation are made to enhance catalytic performance. Here, it is reported the loading of sub-2 nm Ru nanocrystals (NCs) on titanium nitride support (HTS-Ru-NCs/TiN) via a special Ru-Ti interaction using the high-temperature shock (HTS) method. Direct dechlorination of the adsorbed RuCl3, ultrafast nucleation process, and short coalescence duration at ultrahigh temperatures contribute to the immobilization of Ru NCs on TiN support via producing the Ru-Ti interfacial perimeter. HTS-Ru-NCs/TiN shows remarkable activity toward hydrogen evolution reaction (HER) in alkaline solution, yielding ultralow overpotentials of 16.3 and 86.6 mV to achieve 10 and 100 mA cm-2, respectively. The alkaline and anion exchange membrane water electrolyzers assembled using HTS-Ru-NCs/TiN yield 1.0 A cm-2 at 1.65 and 1.67 V, respectively, which validate its applicability in the hydrogen production industry. Theoretical simulations reveal the favorable formation of Ru & horbar;O and Ti & horbar;H bonds at the interfacial perimeters between Ru NCs and TiN, which accelerates the prerequisite water dissociation kinetics for enhanced HER activity. This exemplified work motivates the design of specific interfacial perimeters via the HTS strategy to improve the performance of diverse catalysis. The direct dechlorination of the adsorbed RuCl3, ultrafast nucleation process, and short coalescence duration under high-temperature shock conditions give rise to Sub-2 nm Ru nanocrystals (NCs) on TiN support (HTS-Ru-NCs/TiN) via the specific Ru-Ti interaction. The accelerated water dissociation kinetics at the Ru-Ti interfacial perimeters predominantly account for the encouraging electrocatalytic hydrogen evolution reaction activity in alkaline. image |
| WOS关键词 | METAL-SUPPORT INTERACTIONS ; TEMPERATURE ; CATALYSTS ; PHASE |
| 资助项目 | National Natural Science Foundation of China[52172208] ; National Natural Science Foundation of China[52272222] ; National Natural Science Foundation of China, China[ZR2019JQ14] ; Outstanding Youth Foundation of Shandong Province, China[2019KJC004] ; Youth Innovation and Technology Foundation of Shandong Higher Education Institutions, China[2019JZZY020405] ; Major Scientific and Technological Innovation Project[tsqn201909114] ; Major Scientific and Technological Innovation Project[tsqn202306216] ; Taishan Scholar Young Talent Program[2023HWYQ-091] ; Shandong Excellent Young Scientists Fund Program (Overseas)[ts20190402] ; Taishan Scholar Talent Program |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001241600700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/186041]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 通讯作者 | Wang, Lei |
| 作者单位 | 1.Univ New South Wales, Sch Chem Engn, Kensington, NSW 2052, Australia 2.Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266042, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 4.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Technol Innovat Ctr Battery Safety & Energy Storag, Int Cooperat United Lab Ecochem Engn & Green Mfg, Qingdao 266042, Peoples R China 5.Griffith Univ, Ctr Catalysis & Clean Energy, Gold Coast Campus, Gold Coast, Qld 4222, Australia |
| 推荐引用方式 GB/T 7714 | Zong, Lingbo,Lu, Fenghong,Li, Ping,et al. Thermal Shock Synthesis for Loading Sub-2 nm Ru Nanoclusters on Titanium Nitride as a Remarkable Electrocatalyst toward Hydrogen Evolution Reaction[J]. ADVANCED MATERIALS,2024:9. |
| APA | Zong, Lingbo.,Lu, Fenghong.,Li, Ping.,Fan, Kaicai.,Zhan, Tianrong.,...&Wang, Lei.(2024).Thermal Shock Synthesis for Loading Sub-2 nm Ru Nanoclusters on Titanium Nitride as a Remarkable Electrocatalyst toward Hydrogen Evolution Reaction.ADVANCED MATERIALS,9. |
| MLA | Zong, Lingbo,et al."Thermal Shock Synthesis for Loading Sub-2 nm Ru Nanoclusters on Titanium Nitride as a Remarkable Electrocatalyst toward Hydrogen Evolution Reaction".ADVANCED MATERIALS (2024):9. |
入库方式： OAI收割
来源：海洋研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。