Ozone Formation at a Suburban Site in the Pearl River Delta Region, China: Role of Biogenic Volatile Organic Compounds
文献类型：期刊论文
| 作者 | Wang, Jun2,3,4; Zhang, Yanli1,3,4 ; Xiao, Shaoxuan2,3,4; Wu, Zhenfeng2,3,4; Wang, Xinming1,2,3,4
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| 刊名 | ATMOSPHERE
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| 出版日期 | 2023 |
| 卷号 | 14期号:4页码:609 |
| 关键词 | ATMOSPHERIC OXIDATION CAPACITY MASTER CHEMICAL MECHANISM GROUND-LEVEL OZONE MCM V3 PART SURFACE OZONE AIR-POLLUTION VOC EMISSIONS TROPOSPHERIC DEGRADATION SOURCE APPORTIONMENT RADICAL CHEMISTRY |
| ISSN号 | 2073-4433 |
| DOI | 10.3390/atmos14040609 |
| 英文摘要 | Ozone (O3) is becoming an increasingly concerning air quality problem in China, and previous O3 control strategies focused primarily on reducing anthropogenic volatile organic compounds (AVOCs), while neglecting the role of biogenic VOCs (BVOCs) in O3 formation. In this study, a field campaign was conducted at a suburban site in the Pearl River Delta region of China with high BVOC emissions from 29 August to 3 September 2020. An empirical kinetic modelling approach (EKMA) showed that VOC-limited was the dominant feature for O3 formation at the site. The relative incremental reactivity (RIR) values calculated by the box model (AtChem2-MCM) revealed that isoprene, formaldehyde, methylglyoxal and acetaldehyde had the highest RIRs. Simulation results from the box model also showed that isoprene played a substantial role in the formation of secondary carbonyls, especially contributing 32–92% to the formaldehyde production rate. Box model simulations further showed that during the O3 pollution period with high BVOC emissions, only near zero AVOC emissions could prevent O3 if the levels of nitrogen oxides (NOx) remained unchanged. The results suggest that the presence of high BVOC emissions can greatly impact efforts to control O3 by reducing AVOCs, particularly in regions with relatively high NOx levels (up to 51 ppbv in this study). In the long term, it may be essential to control NOx and choose low BVOC-emitting tree species in urban planning to address this issue, particularly as BVOC emissions are projected to become a more significant source of reactive VOCs with enhanced control of AVOCs. ? 2023 by the authors. |
| WOS研究方向 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000978129800001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/80316]  |
| 专题 | 有机地球化学国家重点实验室 |
| 作者单位 | 1.Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen; 361021, China 2.University of Chinese Academy of Sciences, Beijing; 100049, China 3.CAS Center for Excellence in Deep Earth Science, Guangzhou; 510640, China 4.State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou; 510640, China |
| 推荐引用方式 GB/T 7714 | Wang, Jun,Zhang, Yanli,Xiao, Shaoxuan,et al. Ozone Formation at a Suburban Site in the Pearl River Delta Region, China: Role of Biogenic Volatile Organic Compounds[J]. ATMOSPHERE,2023,14(4):609. |
| APA | Wang, Jun,Zhang, Yanli,Xiao, Shaoxuan,Wu, Zhenfeng,&Wang, Xinming.(2023).Ozone Formation at a Suburban Site in the Pearl River Delta Region, China: Role of Biogenic Volatile Organic Compounds.ATMOSPHERE,14(4),609. |
| MLA | Wang, Jun,et al."Ozone Formation at a Suburban Site in the Pearl River Delta Region, China: Role of Biogenic Volatile Organic Compounds".ATMOSPHERE 14.4(2023):609. |
入库方式： OAI收割
来源：广州地球化学研究所
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