The complex heterogeneous Fenton reactivity of transition metal-doped ferrihydrite: Insight from the structural variation and pathway of H2O2 activation
文献类型：期刊论文
| 作者 | Xie, Qingru3,4; Zhu, Yanping2,4; Xian, Haiyang3,4; Chen, Qingze3,4; Liu, Chengshuai1,3; Wu, Fei1,3; Liang, Xiaoliang3,4 ; Zhu, Runliang3,4
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| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2023 |
| 卷号 | 622页码:156913 |
| 关键词 | IMPURITY-BEARING FERRIHYDRITE SURFACE-STRUCTURE OXYGEN VACANCIES METHYLENE-BLUE IRON OXIDATION REDUCTION CO DEGRADATION MAGNETITE |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2023.156913 |
| 英文摘要 | Doping transition metal into ferrihydrite (Fh) may significantly affect its structure and Fenton reactivity. The comparative study of Fh and M(II)-Fh (M = Cu, Co, or Mn), for the first time, reveals that doping metal ions can alter the property and content of oxygen vacancy (OVs) and the oxidation potential of Fh, which subsequently affects H2O2 decomposition, HO. generation, and Fenton reactivity of the catalysts. The overall Fenton activity of the samples in decomposing bisphenol A decreases in the order Cu-Fh > Fh > Co-Fh > Mn-Fh. In specific, Cu-Fh is the most efficient catalyst as it has the lowest energy barrier for decomposing H2O2 into HO. at OVs sites and the highest oxidation potential (benefiting the reduction of Fe(III) to Fe(II) by H2O2). Our findings show the complex heterogeneous Fenton reactivity of M-Fh, and doping can be an efficient strategy for achieving highly efficient Fenton catalysts. ? 2023 Elsevier B.V. |
| WOS研究方向 | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000974161400001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/80196]  |
| 专题 | 中国科学院矿物学与成矿学重点实验室 |
| 作者单位 | 1.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang; 550081, China 2.Guangdong Provincial Key Laboratory of Agricultural & Rural Pollution Abatement and Environmental Safety, College of Natural Resources and Environment, South China Agricultural University, Guangzhou; 510642, China 3.University of Chinese Academy of Sciences, Beijing; 100049, China 4.CAS Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences (CAS), Guangzhou; 510640, China |
| 推荐引用方式 GB/T 7714 | Xie, Qingru,Zhu, Yanping,Xian, Haiyang,et al. The complex heterogeneous Fenton reactivity of transition metal-doped ferrihydrite: Insight from the structural variation and pathway of H2O2 activation[J]. APPLIED SURFACE SCIENCE,2023,622:156913. |
| APA | Xie, Qingru.,Zhu, Yanping.,Xian, Haiyang.,Chen, Qingze.,Liu, Chengshuai.,...&Zhu, Runliang.(2023).The complex heterogeneous Fenton reactivity of transition metal-doped ferrihydrite: Insight from the structural variation and pathway of H2O2 activation.APPLIED SURFACE SCIENCE,622,156913. |
| MLA | Xie, Qingru,et al."The complex heterogeneous Fenton reactivity of transition metal-doped ferrihydrite: Insight from the structural variation and pathway of H2O2 activation".APPLIED SURFACE SCIENCE 622(2023):156913. |
入库方式： OAI收割
来源：广州地球化学研究所
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