Ionic liquid-functionalized halloysite as an efficient catalyst for the production of 5-hydroxymethylfurfural
文献类型：期刊论文
| 作者 | Sadjadi, Samahe4; Abedian-Dehaghani, Neda3; Zhong, Xuemin2; Heravi, Majid M.3; Yuan, Peng1 |
| 刊名 | APPLIED CLAY SCIENCE
 |
| 出版日期 | 2023 |
| 卷号 | 237页码:106896 |
| 关键词 | CARBONACEOUS CATALYST FRUCTOSE CONVERSION DEHYDRATION NANOTUBES NANOPARTICLES GLUCOSE TRANSFORMATION SUPPORT 5-HMF |
| ISSN号 | 0169-1317 |
| DOI | 10.1016/j.clay.2023.106896 |
| 英文摘要 | Three different acidic ionic liquids were covalently grafted on halloysite to give heterogeneous catalysts. The acidity of the catalysts was higher than halloysite and differed based on the nature of ionic liquid. Investigation of the catalytic activity of the catalysts for the synthesis of 5-hydroxymethylfurfural indicates that imidazolium-based ionic liquid showed the highest activity. Using this catalyst (30 wt%), 5-hydroxymethylfurfural was achieved from dehydration of fructose in 88% yield at 85 °C in 73 min. Furthermore, the catalyst was recyclable up to six runs with slight loss of activity. Comparison of the performance of the catalyst with halloysite-free counterpart confirmed the role of halloysite in improvement of the catalytic activity and recyclability. ? 2023 Elsevier B.V. |
| WOS研究方向 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Mineralogy |
| 语种 | 英语 |
| WOS记录号 | WOS:000952130800001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/80226]  |
| 专题 | 中国科学院矿物学与成矿学重点实验室 |
| 作者单位 | 1.School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou; 510006, China 2.CAS Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou; 510640, China 3.Department of Chemistry, School of physic and chemistry, Alzahra University, PO Box 1993891176, Vanak, Tehran, Iran 4.Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, PO Box 14975-112, Tehran, Iran |
| 推荐引用方式 GB/T 7714 | Sadjadi, Samahe,Abedian-Dehaghani, Neda,Zhong, Xuemin,et al. Ionic liquid-functionalized halloysite as an efficient catalyst for the production of 5-hydroxymethylfurfural[J]. APPLIED CLAY SCIENCE,2023,237:106896. |
| APA | Sadjadi, Samahe,Abedian-Dehaghani, Neda,Zhong, Xuemin,Heravi, Majid M.,&Yuan, Peng.(2023).Ionic liquid-functionalized halloysite as an efficient catalyst for the production of 5-hydroxymethylfurfural.APPLIED CLAY SCIENCE,237,106896. |
| MLA | Sadjadi, Samahe,et al."Ionic liquid-functionalized halloysite as an efficient catalyst for the production of 5-hydroxymethylfurfural".APPLIED CLAY SCIENCE 237(2023):106896. |
入库方式： OAI收割
来源：广州地球化学研究所
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