The oxidation of NH3/CO/O2/H2O system in a plug flow reactor: Experimental and kinetic modeling study
文献类型：期刊论文
| 作者 | Chen, Qingqing1,2; Zhao, Jing1,2 ; Zhang, Zirui1,2; Wei, Xiaolin1,2; Wei XL(魏小林); Zhao J(赵京)
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| 刊名 | FUEL
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| 出版日期 | 2025 |
| 卷号 | 379页码:9 |
| 关键词 | Ammonia Flow reactor NH (3)/CO co-combustion Detailed kinetics NO |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2024.133039 |
| 通讯作者 | Wei, Xiaolin(xlwei@imech.ac.cn) |
| 英文摘要 | Ammonia, as a carbon-free fuel, is easier to store and transport than hydrogen. Due to the high ignition energy and low reactivity of ammonia, adding hydrogen or carbon-based fuels as combustion aids may improve the ignition and burnout of ammonia. CO is an important intermediate product in the co-combustion process of ammonia and carbon-based fuels. Research on NH3/CO co-combustion will further promote the application of such co-fuel in propulsion systems and power generation. In this work, experimental results were supplemented with novel flow reactor results on the effect of NH3 on CO oxidation in the absence of NO, and explained based on a detailed chemical kinetic model. The effects of temperature (1023-1223 K), NH3 concentration (250-1500 ppm), and water content (1 %-10 %) on CO oxidation, NH3 conversion, and NO generation were analyzed. In the NH3/CO system, the properties of CO always dominate. As the NH3 content increases, NH3 gradually inhibits the oxidation of CO by seizing free radicals (O, H, OH) and converting into NH2. NH2 further interacts with free radicals to convert into NH or HNO, and ultimately into NO. An increase in temperature will decrease the release of NO and CO and gradually decrease the conversion of NO from NH3. However, ammonia concentration had little effect on the ratio of ammonia conversion to NO. When H2O increases from 1 % to 2 %, it has a significant inhibitory effect on the production of NO and promotes the oxidation of CO. When the water concentration increases from 5 % to 10 %, the inhibitory effect reaches saturation. The present work evaluates the amine subset of the reaction mechanism under the studied conditions and provides experimental data under different NH3/CO ratios, which can be used to construct and verify the reaction mechanism of mixed fuels of carbon-based fuels and ammonia. |
| WOS关键词 | LAMINAR BURNING VELOCITIES ; NITROGEN CHEMISTRY ; AMMONIA ; NO ; NH3 ; COMBUSTION ; MECHANISM ; MIXTURES ; HYDROGEN ; NH3/SYNGAS/AIR |
| 资助项目 | National Natural Science Foundation of China[52176142] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001311799900001 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/96587]  |
| 专题 | 力学研究所_高温气体动力学国家重点实验室 |
| 通讯作者 | Wei, Xiaolin |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Engn & Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qingqing,Zhao, Jing,Zhang, Zirui,et al. The oxidation of NH3/CO/O2/H2O system in a plug flow reactor: Experimental and kinetic modeling study[J]. FUEL,2025,379:9. |
| APA | Chen, Qingqing,Zhao, Jing,Zhang, Zirui,Wei, Xiaolin,魏小林,&赵京.(2025).The oxidation of NH3/CO/O2/H2O system in a plug flow reactor: Experimental and kinetic modeling study.FUEL,379,9. |
| MLA | Chen, Qingqing,et al."The oxidation of NH3/CO/O2/H2O system in a plug flow reactor: Experimental and kinetic modeling study".FUEL 379(2025):9. |
入库方式： OAI收割
来源：力学研究所
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