Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries
文献类型：期刊论文
| 作者 | Guo, Qiang; Mo WX(莫伟兴); Huang, Jianhang; Liu F(刘峰) |
| 刊名 | NANO LETTERS
 |
| 出版日期 | 2024-11 |
| 关键词 | deep eutectic electrolyte solvation structure inorganic-rich interphase Zn anode |
| ISSN号 | 1530-6984 |
| DOI | 10.1021/acs.nanolett.4c03480 |
| 英文摘要 | Highly stable aqueous Zn-ion batteries are of great importance for commercial applications. The challenging issues of interfacial side reactions and rampant dendrite growth cause short circuit and premature failure of aqueous Zn-ion batteries. Herein, a hydrated deep eutectic electrolyte is formulated to tackle such problems, which adopts 1,3-propanediol as a cosolvent. 1,3-Propanediol molecules can enter into the Zn2+ solvation structure to from a lean-water electrolyte and drastically diminish the activity of water molecules through reinforcing the hydrogen bond network. Meanwhile, PDO molecules exclude the neighboring water to modulate the electric double layer configuration, thus impeding water-mediated side reactions and inducing an inorganic-rich interphase. Consequently, this hydrated deep eutectic electrolyte ensures long-term stability of Zn-Zn, Zn-Cu, and Zn-I2 cells. The favorable influence exerted by PDO molecules provides the guidance for constructing high-performance aqueous Zn-ion batteries. |
| 分类号 | 一类 |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001357805300001 |
| 资助机构 | Zhejiang Normal University ; Zhejiang Normal University |
| 其他责任者 | Guo Q ; Liu F |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/97232]  |
| 专题 | 力学研究所_非线性力学国家重点实验室 |
| 作者单位 | 1.【Huang, Jianhang】 Zhejiang Normal Univ, Coll Chem & Mat Sci, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China 2.【Mo, Weixing & Liu, Feng】 Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China 3.【Guo, Qiang】 Zhejiang Normal Univ, Inst Sci & Applicat Mol Ferroelect, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Qiang,Mo WX,Huang, Jianhang,et al. Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries[J]. NANO LETTERS,2024. |
| APA | Guo, Qiang,莫伟兴,Huang, Jianhang,&刘峰.(2024).Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries.NANO LETTERS. |
| MLA | Guo, Qiang,et al."Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries".NANO LETTERS (2024). |
入库方式： OAI收割
来源：力学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。