Improving Li Ion Storage Capability of V2O5 Electrode by Using Aminoalkyldisiloxane Electrolyte Additive
文献类型：期刊论文
| 作者 | Li, Youpeng1,2; Zhang, Lingzhi1
|
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2022-09-06 |
| 卷号 | 7期号:33页码:7 |
| 关键词 | electrolyte interphase layer V2O5 aminoakyldisiloxane Li+ storage capability |
| ISSN号 | 2365-6549 |
| DOI | 10.1002/slct.202202877 |
| 通讯作者 | Zhang, Lingzhi(lzzhang@ms.giec.ac.cn) |
| 英文摘要 | The unstable electrolyte interphase layer on the surface of V2O5 limits its Li+ storage capability. Herein, a novel aminoakyldisiloxane compound, (3-(N,N-dimethylamino)diethoxypropyl) pentamethyldisiloxane (DSON), is applied as an efficient electrolyte additive for enhancing the electrochemical performance of V2O5 electrode. DSON additive in the conventional carbonate-based electrolyte can inhibit the generation of acidic species by suppressing the hydrolysis of LiPF6. Additionally, DSON can also induce the formation of solid electrolyte interphase on the surface of V2O5 electrode upon (de)lithiation, which decreases the charge transfer resistance of Li+ at the interface between electrode and electrolyte. Thus, the V2O5 electrode with the electrolyte containing DSON additive (0.5 wt%) delivers a higher specific capacity (311.8 mAh g-1 at 0.1 C), excellent cycling performance (248.1 mAh g(-1) at 0.5 C after 250 cycles) and rate performance (235.9 mAh g(-1) at 2 C). This work demonstrates that aminoakyldisiloxane is an effective electrolyte additive to stabilize the surface electrolyte film and improve the Li+ storage capability of metallic oxide-based electrode materials. |
| WOS关键词 | ELECTROCHEMICAL PERFORMANCE ; CATHODE MATERIAL ; LITHIUM ; CARBON ; ENABLES |
| 资助项目 | China Postdoctoral Science Foundation[2020M682938] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515110273] ; STS Program of Chinese Academy of Sciences (Dongguan Special Fund)[20211600200331] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000848258000001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | China Postdoctoral Science Foundation ; Guangdong Basic and Applied Basic Research Foundation ; STS Program of Chinese Academy of Sciences (Dongguan Special Fund) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37197]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Lingzhi |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Shunde Polytech, Sch Energy & Automot Engn, Foshan 528300, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Youpeng,Zhang, Lingzhi. Improving Li Ion Storage Capability of V2O5 Electrode by Using Aminoalkyldisiloxane Electrolyte Additive[J]. CHEMISTRYSELECT,2022,7(33):7. |
| APA | Li, Youpeng,&Zhang, Lingzhi.(2022).Improving Li Ion Storage Capability of V2O5 Electrode by Using Aminoalkyldisiloxane Electrolyte Additive.CHEMISTRYSELECT,7(33),7. |
| MLA | Li, Youpeng,et al."Improving Li Ion Storage Capability of V2O5 Electrode by Using Aminoalkyldisiloxane Electrolyte Additive".CHEMISTRYSELECT 7.33(2022):7. |
入库方式： OAI收割
来源：广州能源研究所
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