Conversion of carbon dioxide to carbon monoxide: Two-step chemical looping dry reforming using Ca2Fe2O5-Zr0.5Ce0.5O2 composite oxygen carriers
文献类型：期刊论文
| 作者 | Wang, Luwen2,3; Lin, Yan2; Huang, Zhen2; Zeng, Kuo3; Huang, Hongyu1,2 |
| 刊名 | FUEL
 |
| 出版日期 | 2022-08-15 |
| 卷号 | 322页码:9 |
| 关键词 | Chemical looping dry reforming (CLDR) Oxygen carrier CO2 splitting Ca2Fe2O5 Zr0.5Ce0.5O2 |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2022.124182 |
| 通讯作者 | Huang, Zhen(huangzhen@ms.giec.ac.cn) ; Zeng, Kuo(zengkuo666@hust.edu.cn) |
| 英文摘要 | In this study, Zr0.5Ce0.5O2 (ZC) was used to improve the reactivity of Ca2Fe2O5 (CF) oxygen carriers (OCs) and alleviate sintering. The reactivity of modified OCs in Chemical looping dry reforming (CLDR) was explored using a thermogravimetric analyzer and a fixed-bed reactor, and the fresh and reacted OCs were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results revealed that CF6 (60 wt% CF + 40 wt% ZC) had the best reactivity. Owing to the addition of ZC, the carbon monoxide (CO) yield of CF6 was twice that of CF during carbon dioxide (CO2) oxidation, increasing from 72.3 mL/g to 138 mL/g. In the cyclic experiments, the CO yield from CO2 oxidation decreased from 138 mL/g in the first cycle to 34.3 mL/g in the fifth cycle and subsequently stabilized over the next 15 cycles. The decrease in cyclic performance is related to the sintering of the sample and the formation of a new phase, CaZrO3, which hindered the redox reaction in the sample. Although CF6 had a decreased cyclic performance, it still had a better reactivity than CF, which had a CO yield that was about 20% lower than that of CF6. The reason for the improvement is that ZC improved the dispersibility of CF. After 20 cycles, the generation of CO was facilitated by extending the reduction time of the OC, and the CO yield increased from 35 mL/g to 60 mL/g when the reduction time was doubled. |
| WOS关键词 | HYDROGEN-PRODUCTION ; CO2 CAPTURE ; CA2FE2O5 ; CERIA ; ENHANCEMENT ; KINETICS ; MODE |
| 资助项目 | National Natural Science Foundation of China[52076209] ; National Natural Science Foundation of China[51776210] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0108] ; Guangdong Basic and Applied Basic Research Foundation[2019B1515120022] ; Youth Innovation Promotion Association, CAS[2018384] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000856126000002 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Guangdong Basic and Applied Basic Research Foundation ; Youth Innovation Promotion Association, CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37285]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Huang, Zhen; Zeng, Kuo |
| 作者单位 | 1.Southern Marine Sci & Engn Guangdong Lab Guangzho, 1119 Haibin Rd, Guangzhou 511458, Peoples R China 2.Chinese Acad Sci, CAS, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 3.Huazhong Univ Sci & Technol, Sch Energy & Power Engn, State Key Lab Coal Combust, Wuhan 430074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Luwen,Lin, Yan,Huang, Zhen,et al. Conversion of carbon dioxide to carbon monoxide: Two-step chemical looping dry reforming using Ca2Fe2O5-Zr0.5Ce0.5O2 composite oxygen carriers[J]. FUEL,2022,322:9. |
| APA | Wang, Luwen,Lin, Yan,Huang, Zhen,Zeng, Kuo,&Huang, Hongyu.(2022).Conversion of carbon dioxide to carbon monoxide: Two-step chemical looping dry reforming using Ca2Fe2O5-Zr0.5Ce0.5O2 composite oxygen carriers.FUEL,322,9. |
| MLA | Wang, Luwen,et al."Conversion of carbon dioxide to carbon monoxide: Two-step chemical looping dry reforming using Ca2Fe2O5-Zr0.5Ce0.5O2 composite oxygen carriers".FUEL 322(2022):9. |
入库方式： OAI收割
来源：广州能源研究所
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