Highly selective photocatalytic oxidation of alcohols under the application of novel metal organic frameworks (MOFs) based catalytic system
文献类型：期刊论文
| 作者 | Wei, Xiu-Zhi3,5; Dagnaw, Fentahun Wondu2; Liu, Jianguo1,4; Ma, Longlong1,4,5
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| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2023 |
| 卷号 | 629页码:136-143 |
| 关键词 | Carboxylic acids Photocatalytic oxidation Cocatalyst MOFs |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2022.08.119 |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Carboxylic acid is one of the most crucial and widely used organic chemicals in daily human life activities. Hence preparation of this important chemical was performed under the application of the highly selective photo-catalysts through oxidation of alcohols to carboxylic acids. Herein, we have designed and dis-closed a binary NH2-MIL-125(Ti)/ NaBr) catalyst system to realize the effective transformation of alcohols into carboxylic acids under visible light irradiation. Hence, derivatives of benzyl alcohol containing either electron withdrawing and donating groups as well as aliphatic primary alcohols were effectively converted into the corresponding carboxylic acids. Based on our findings, NH2-MIL-125(Ti) based photocatalytic system has shown efficient and highly selective activities for oxidation of alcohol especially the in-situ conversion of co-catalyst NaBr into the corresponding free radical can enhance the alcohol oxidation performance of the catalytic system. (c) 2022 Elsevier Inc. All rights reserved. |
| WOS关键词 | AEROBIC OXIDATION ; GOLD NANOPARTICLES ; BENZYL ALCOHOL ; AROMATIC ALCOHOLS ; CARBOXYLIC-ACIDS ; PHOTOOXIDATION ; REDUCTION ; ALDEHYDES ; CLEAVAGE ; AMINES |
| 资助项目 | National Key R&D Program of China[2018YFB1501500] ; National Natural Science Foundation of China[51976225] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000860519200003 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37425]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo; Ma, Longlong |
| 作者单位 | 1.Univ Sci & Technol China, Dept Engn Sci, Hefei 230026, Peoples R China 2.Bahir Dar Univ, Dept Chem, Bahir Dar, Ethiopia 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 5.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Xiu-Zhi,Dagnaw, Fentahun Wondu,Liu, Jianguo,et al. Highly selective photocatalytic oxidation of alcohols under the application of novel metal organic frameworks (MOFs) based catalytic system[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2023,629:136-143. |
| APA | Wei, Xiu-Zhi,Dagnaw, Fentahun Wondu,Liu, Jianguo,&Ma, Longlong.(2023).Highly selective photocatalytic oxidation of alcohols under the application of novel metal organic frameworks (MOFs) based catalytic system.JOURNAL OF COLLOID AND INTERFACE SCIENCE,629,136-143. |
| MLA | Wei, Xiu-Zhi,et al."Highly selective photocatalytic oxidation of alcohols under the application of novel metal organic frameworks (MOFs) based catalytic system".JOURNAL OF COLLOID AND INTERFACE SCIENCE 629(2023):136-143. |
入库方式： OAI收割
来源：广州能源研究所
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