Selectivity catalytic transfer hydrogenation of biomass-based furfural to cyclopentanone
文献类型：期刊论文
| 作者 | Li, Hao3,4; Liu, Jia3; Cai, Chiliu3 ; Wang, Haiyong3; Huang, Youwang2; Wang, Chenguang3; Ma, Longlong1
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| 刊名 | FUEL
 |
| 出版日期 | 2023-01-15 |
| 卷号 | 332页码:7 |
| 关键词 | Furfural Cyclopentanone Cyclopentanol Encapsulated N -doped Hydrogenation |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2022.126057 |
| 通讯作者 | Wang, Haiyong(wanghy@ms.giec.ac.cn) ; Huang, Youwang(2022021@hebut.edu.cn) |
| 英文摘要 | Because of furfural's diverse unsaturated groups and the rearrangement of oxygen atoms, the production of cyclopentanone (CPO) from furfural (FF) can be challenging. Herein, a novel nitrogen-doped encapsulated catalyst (Co@NC) was synthesized to catalyze the selective hydrogenation of FF in an aqueous phase to CPO. A CPO yield of 86.5 % was obtained at 200 degrees C and 3 MPa H2. Meanwhile, furfuryl alcohol (FA) was inferred to be the primary intermediate in the formation of CPO and cyclopentanol (CPL). CPL originated from the further hydrogenation of CPO that was produced via FF selective hydrogenation to FA, followed by FA hydro-deoxgenation to CPO. The main presence of CPO illustrated that it avoided overhydrogenation, which contrib-uted to the tailored hydrogenation ability of Co@NC and facilitated the selective preservation of C--O bonds. The N atoms acting as electronegative heteroatoms can not only enhance the adsorption of FF but also provide weak Lewis acid sites for CPO production. |
| WOS关键词 | OXYGEN REDUCTION ; POROUS CARBONS ; EFFICIENT ; NANOPARTICLES ; EVOLUTION ; CHEMICALS ; GRAPHENE ; CO ; ELECTROCATALYSTS ; NANOCRYSTALS |
| 资助项目 | National Natural Science Foundation of China ; R & D Plan of Key Fields in Guangdong Province ; Natural Science Foundation of Guangdong Province ; [52006225] ; [52236010] ; [52006228] ; [2020B1111570001] ; [2018A030310135] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000866232400003 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; R & D Plan of Key Fields in Guangdong Province ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37468]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Haiyong; Huang, Youwang |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 2.Hebei Univ Technol, Coll Chem Engn, Tianjin 300401, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 4.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hao,Liu, Jia,Cai, Chiliu,et al. Selectivity catalytic transfer hydrogenation of biomass-based furfural to cyclopentanone[J]. FUEL,2023,332:7. |
| APA | Li, Hao.,Liu, Jia.,Cai, Chiliu.,Wang, Haiyong.,Huang, Youwang.,...&Ma, Longlong.(2023).Selectivity catalytic transfer hydrogenation of biomass-based furfural to cyclopentanone.FUEL,332,7. |
| MLA | Li, Hao,et al."Selectivity catalytic transfer hydrogenation of biomass-based furfural to cyclopentanone".FUEL 332(2023):7. |
入库方式： OAI收割
来源：广州能源研究所
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