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Unraveling abiotic organic synthesis pathways in the mafic crust of mid- ocean ridges

文献类型：期刊论文

作者Nan, Jingbo12,13,14; Peng, Xiaotong14; Plumper, Oliver11; ten Have, Iris C.10; Lu, Jing- Guang9; Liu, Qian-Bao9; Li, Shao-Lin8; Hu, Yingjie7; Liu, Yu6; Shen, Zhen6
刊名PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
出版日期2024-10-22
卷号121期号:43页码:8
关键词low- temperature alteration of oceanic crust |abiotic organic synthesis organic condensation mineral- catalyzed reaction deep carbon cycle
ISSN号0027-8424
DOI10.1073/pnas.2308684121
英文摘要The aqueous alteration of the oceanic lithosphere provides significant energy that impacts the synthesis and diversity of organic compounds, which are crucial for the deep carbon cycle and may have provided the first building blocks for life. Although abiotic organic synthesis has been documented in mantle- derived rocks, the formation mechanisms and complexity of organic compounds in crustal rocks remain largely unknown. Here, we show the specific association of aliphatic carbonaceous matter with Fe oxyhydroxides in mafic crustal rocks of the Southwest Indian Ridge (SWIR). We determine potential Fe- based pathways for abiotic organic synthesis from CO2 and H2 using multimodal and molecular nano- geochemical tools. Quantum mechanical modeling is further employed to constrain the catalytical activity of Fe oxyhydroxides, revealing that the catalytic cycle of hydrogen may play a key role in carbon-carbon bond formation. This approach offers the possibility of interpreting physicochemical organic formation and condensation mechanisms at an atomic scale. The findings expand our knowledge of the existence of abiotic organic carbon in the oceanic crustal rocks and emphasize the mafic oceanic crust of the SWIR as a potential site for low- temperature abiotic organic synthesis.
WOS关键词FISCHER-TROPSCH SYNTHESIS ; CARBON ; SERPENTINITES ; FLUXES ; TIME ; IRON ; HYDROCARBONS ; SURFACES ; CATALYST ; WATER
资助项目National Key Research and Development Program of China[2016YFC0302301] ; National Natural Science Foundation of China[42106069] ; European Research Council[852069] ; Dutch Research Council (NWO) Vidi grant[Vidi.193.030]
WOS研究方向Science & Technology - Other Topics
语种英语
WOS记录号WOS:001352098000001
出版者NATL ACAD SCIENCES
资助机构National Key Research and Development Program of China ; National Natural Science Foundation of China ; European Research Council ; Dutch Research Council (NWO) Vidi grant
源URL[http://ir.idsse.ac.cn/handle/183446/11805]  
专题深海科学研究部_深海地质与地球化学研究室
专家咨询委员会
通讯作者Peng, Xiaotong
作者单位1.Max Planck Inst Terr Microbiol, Geochem Protoenzymes Res Grp, D-35043 Marburg, Germany
2.Ctr Synthet Microbiol, D-35032 Marburg, Germany
3.Philipps Univ Marburg, D-35032 Marburg, Germany
4.Max Planck Inst Terr Microbiol, Microcosm Earth Ctr, D-35032 Marburg, Germany
5.Southern Univ Sci & Technol, Dept Ocean Sci & Engn, Shenzhen 518055, Peoples R China
6.China Univ Min & Technol Beijing, Coll Geosci & Surveying Engn, Beijing 100083, Peoples R China
7.Nanjing Xiaozhuang Univ, Nanjing Key Lab Adv Funct Mat, Nanjing 211171, Peoples R China
8.Macau Univ Sci & Technol, State Key Lab Lunar & Planetary Sci, Taipa, Macau, Peoples R China
9.Macau Univ Sci & Technol, Macau Inst Appl Res Med & Hlth, State Key Lab Qual Res Chinese Med, Taipa 999078, Macau, Peoples R China
10.Univ Utrecht, Fac Sci, Debye Inst Nanomat Sci, NL-3584 CG Utrecht, Netherlands
推荐引用方式
GB/T 7714		 Nan, Jingbo,Peng, Xiaotong,Plumper, Oliver,et al. Unraveling abiotic organic synthesis pathways in the mafic crust of mid- ocean ridges[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2024,121(43):8.
APA Nan, Jingbo.,Peng, Xiaotong.,Plumper, Oliver.,ten Have, Iris C..,Lu, Jing- Guang.,...&Luo, Yongxiang.(2024).Unraveling abiotic organic synthesis pathways in the mafic crust of mid- ocean ridges.PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,121(43),8.
MLA Nan, Jingbo,et al."Unraveling abiotic organic synthesis pathways in the mafic crust of mid- ocean ridges".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 121.43(2024):8.

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来源：深海科学与工程研究所

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