Controls of the Nucleation Rate and Advection Rate on Barite Precipitation in Fractured Porous Media
文献类型：期刊论文
| 作者 | Jiang, QiuRong4,5; Hu, Ran4,5; Deng, Hang3; Ling BW(凌博闻)1,2; Yang, Zhibing4,5; Chen, YiFeng4,5 |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2025-01-09 |
| 卷号 | 41期号:2页码:1250-1259 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/acs.langmuir.4c03532 |
| 通讯作者 | Hu, Ran(whuran@whu.edu.cn) ; Deng, Hang(hangdeng@pku.edu.cn) |
| 英文摘要 | Mineral precipitation is ubiquitous in natural and engineered environments, such as carbon mineralization, contaminant remediation, and oil recovery in unconventional reservoirs. The precipitation process continuously alters the medium permeability, thereby influencing fluid transport and subsequent reaction kinetics. The diversity of preferential precipitation zones controls flow and transport efficiency as well as the capacity of mineral sequestration and immobilization. Taking barite precipitation as an example, previous studies have examined this process in porous and/or fractured media, but pore-scale mechanisms under varying flowing and geochemical conditions remain unexplored. In this study, we conducted real-rock microfluidic experiments to investigate the precipitation dynamics within a fractured porous system. Direct observations of the evolution of the porous structure and flow channel and quantifications of barite precipitation dynamics using X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), revealed two distinct precipitation regimes: precipitation on the fracture surface (regime I) and precipitation in the alteration zone (regime II). Through theoretical analysis of the rate of advection and nucleation, we defined a dimensionless number Da above which regime I occurs and regime II prevails otherwise. At the large Da number, when the precipitation rate is large compared with the flow rate, precipitation on the fracture surface is favored. As the precipitation regimes are expected to impact differently the permeability of the fractured porous media, the mass transfer across matrix and fractures, and the spatial distributions of coprecipitated contaminants, our work sheds light on accurately modeling reactive transport in fractured porous media across diverse applications. |
| 分类号 | 二类 |
| WOS关键词 | MARCELLUS SHALE ; MINERAL REACTIONS ; EAGLE FORD ; WATER ; DISSOLUTION ; EXPOSURE ; FLUID ; ROCK ; PH |
| 资助项目 | National Natural Science Foundation of China[52379107] ; National Natural Science Foundation of China[42277224] ; National Natural Science Foundation of China[42272158] ; National Natural Science Foundation of China |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001393294300001 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 其他责任者 | Hu, Ran ; Deng, Hang |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/98095]  |
| 专题 | 力学研究所_流固耦合系统力学重点实验室(2012-) |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Mech, Beijing 100190, Peoples R China; 3.Peking Univ, Coll Engn, Dept Energy & Resources Engn, Beijing 100871, Peoples R China; 4.Wuhan Univ, Key Lab Rock Mech Hydraul Struct Engn, Minist Educ, Wuhan 430072, Peoples R China; 5.Wuhan Univ, State Key Lab Water Resources Engn & Management, Wuhan 430072, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Jiang, QiuRong,Hu, Ran,Deng, Hang,et al. Controls of the Nucleation Rate and Advection Rate on Barite Precipitation in Fractured Porous Media[J]. LANGMUIR,2025,41(2):1250-1259. |
| APA | Jiang, QiuRong,Hu, Ran,Deng, Hang,凌博闻,Yang, Zhibing,&Chen, YiFeng.(2025).Controls of the Nucleation Rate and Advection Rate on Barite Precipitation in Fractured Porous Media.LANGMUIR,41(2),1250-1259. |
| MLA | Jiang, QiuRong,et al."Controls of the Nucleation Rate and Advection Rate on Barite Precipitation in Fractured Porous Media".LANGMUIR 41.2(2025):1250-1259. |
入库方式： OAI收割
来源：力学研究所
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