Bidentate Coordination Structure Facilitates High-Voltage and High-Utilization Aqueous Zn-I2 Batteries
文献类型：期刊论文
| 作者 | Wang, Mingming1; Meng, Yahan1; Sajid, Muhammad1; Xie, Zehui1; Tong, Peiyan1; Ma, Zhentao3; Zhang, Kai1; Shen, Dongyang1; Luo, Ruihao1; Song, Li1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2024-08-25 |
| 关键词 | Zn-I-2 battery Zn anode Iodine cathode Bidentate coordination structure High ZUR |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202404784 |
| 通讯作者 | Zheng, Xusheng(zxs@ustc.edu.cn) ; Li, Xiangyang(xyangli@ustc.edu.cn) ; Chen, Wei(weichen1@ustc.edu.cn) |
| 英文摘要 | The aqueous zinc-iodine battery is a promising energy storage device, but the conventional two-electron reaction potential and energy density of the iodine cathode are far from meeting practical application requirements. Given that iodine is rich in redox reactions, activating the high-valence iodine cathode reaction has become a promising research direction for developing high-voltage zinc-iodine batteries. In this work, by designing a multifunctional electrolyte additive trimethylamine hydrochloride (TAH), a stable high-valence iodine cathode in four-electron-transfer I-/I-2/I+ reactions with a high theoretical specific capacity is achieved through a unique amine group, Cl bidentate coordination structure of (TA)ICl. Characterization techniques such as synchrotron radiation, in situ Raman spectra, and DFT calculations are used to verify the mechanism of the stable bidentate structure. This electrolyte additive stabilizes the zinc anode by promoting the desolvation process and shielding mechanism, enabling the zinc anode to cycle steadily at a maximum areal capacity of 57 mAh cm(-2) with 97 % zinc utilization rate. Finally, the four-electron-transfer aqueous Zn-I-2 full cell achieves 5000 stable cycles at an N/P ratio of 2.5. The unique bidentate coordination structure contributes to the further development of high-valence and high capacity aqueous zinc-iodine batteries. |
| WOS关键词 | IODINE MONOCHLORIDE ; COMPLEXES |
| 资助项目 | National Natural Science Foundation of China[92372122] ; National Natural Science Foundation of China[22203086] ; National Natural Science Foundation of China[12222508] ; Fundamental Research Funds for the Central Universities[KY2060000150] ; Fundamental Research Funds for the Central Universities[WK2060000040] ; Postdoctoral Fellowship Program of CPSF[GZB20240708] ; USTC Center for Micro and Nanoscale Research and Fabrication ; NEWARE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001297970700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Postdoctoral Fellowship Program of CPSF ; USTC Center for Micro and Nanoscale Research and Fabrication ; NEWARE |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/135007]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zheng, Xusheng; Li, Xiangyang; Chen, Wei |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Sch Chem & Mat Sci, Dept Appl Chem, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci HFIPS, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China 3.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Mingming,Meng, Yahan,Sajid, Muhammad,et al. Bidentate Coordination Structure Facilitates High-Voltage and High-Utilization Aqueous Zn-I2 Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024. |
| APA | Wang, Mingming.,Meng, Yahan.,Sajid, Muhammad.,Xie, Zehui.,Tong, Peiyan.,...&Chen, Wei.(2024).Bidentate Coordination Structure Facilitates High-Voltage and High-Utilization Aqueous Zn-I2 Batteries.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
| MLA | Wang, Mingming,et al."Bidentate Coordination Structure Facilitates High-Voltage and High-Utilization Aqueous Zn-I2 Batteries".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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