Preparation and performance of long-life PEO-based solid-state batteries based on the complexation of 15 Crown ether 5 with lithium salt
文献类型：期刊论文
| 作者 | Li, Shi Jia1,2,3; Fei, Guang Tao1,2 ; Xu, Shao Hui1,2; Chen, Wen Chao1,2,3; Xu, Hai Yan1,2,3; Qu, Xiao Xuan1,2,3; Li, Xin Feng4; Ouyang, Hao Miao4
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| 刊名 | JOURNAL OF POWER SOURCES
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| 出版日期 | 2024-12-15 |
| 卷号 | 623 |
| 关键词 | Solid-state batteries Lithium-ion batteries PEO solid-state electrolytes 15 crown ether 5 High salt |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2024.235376 |
| 通讯作者 | Fei, Guang Tao(gtfei@issp.ac.cn) ; Xu, Shao Hui(shxu@issp.ac.cn) ; Li, Xin Feng(lixinfeng@gotion.com.cn) |
| 英文摘要 | Poly (ethylene oxide) (PEO)-based solid-state electrolytes are the most researched and widely used polymer solid-state electrolytes, but their ionic conductivity, electrochemical stability window, and cycling stability all need further improvement. In this work, 15 Crown ether 5 and the high concentration of lithium salts are added into PEO solid-state electrolytes using a solution-casting approach. The resulting solid-state electrolyte exhibits an ionic conductivity of 3.14 x 10(-3) S cm(-1) at 60 degrees C and an electrochemical stability window exceeding 5.2 V. The assembled Li//Li symmetric battery can be stably cycled for over 850 h at a current of 0.1 mA cm(-2), and the LiFePO4//Li battery has an initial discharge capacity of 144 mA h g(-1) at 2C rate, retaining 85 % of its capacity after 800 cycles. By optimizing the solid-state electrolyte components, Li//Li symmetric batteries can achieve cycling stability for up to 2200 h, and LiFePO4//Li batteries can endure up to 2000 cycles at a 2C rate and 4800 cycles at a 5C rate. Moreover, the prepared solid-state electrolyte can be matched with a high-voltage cathode electrode, offering a wide range of potential applications and promising commercialization prospects. |
| WOS关键词 | IONIC-CONDUCTIVITY ; ELECTROLYTE ; FILLER |
| 资助项目 | Major Science and Technology Project of Anhui Province, P. R. China[202203a07020026] ; National Natural Science Foundation of China[51971210] ; Natural Sci-ence Foundation of Anhui Province, P. R. China[2208085ME112] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001310468700001 |
| 出版者 | ELSEVIER |
| 资助机构 | Major Science and Technology Project of Anhui Province, P. R. China ; National Natural Science Foundation of China ; Natural Sci-ence Foundation of Anhui Province, P. R. China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/135185]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Fei, Guang Tao; Xu, Shao Hui; Li, Xin Feng |
| 作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Key Lab Mat Phys, POB 1129, Hefei 230031, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Anhui Key Lab Nanomat & Nanotechnol, POB 1129, Hefei 230031, Peoples R China 3.Univ Sci & Technol China, Hefei 230026, Peoples R China 4.Hefei Gotion High Tech Power Energy Co Ltd, Hefei 230000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shi Jia,Fei, Guang Tao,Xu, Shao Hui,et al. Preparation and performance of long-life PEO-based solid-state batteries based on the complexation of 15 Crown ether 5 with lithium salt[J]. JOURNAL OF POWER SOURCES,2024,623. |
| APA | Li, Shi Jia.,Fei, Guang Tao.,Xu, Shao Hui.,Chen, Wen Chao.,Xu, Hai Yan.,...&Ouyang, Hao Miao.(2024).Preparation and performance of long-life PEO-based solid-state batteries based on the complexation of 15 Crown ether 5 with lithium salt.JOURNAL OF POWER SOURCES,623. |
| MLA | Li, Shi Jia,et al."Preparation and performance of long-life PEO-based solid-state batteries based on the complexation of 15 Crown ether 5 with lithium salt".JOURNAL OF POWER SOURCES 623(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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