Biomimetic (Co, Ni, W)OxNy/WO3 x N y /WO3 photoelectrocatalyst for robust seawater oxidation
文献类型：期刊论文
| 作者 | Ma, Guangcai1; Li, Wenbin1; Wang, Fei1; Zhang, Lunyong2; Chen, Bin3,4 ; Yu, Xiujun5; Hu, Wenqing1; Ding, Ting1; Zhou, Baiyang1; Zhang, Zhuo1
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| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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| 出版日期 | 2024-12-05 |
| 卷号 | 1007 |
| 关键词 | Photoelectrocatalyst Seawater splitting N/W-doping CoNi oxide Wo2 |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2024.176490 |
| 通讯作者 | Chen, Bin(bchen@issp.ac.cn) ; Yu, Xiujun(xiujunyu@szu.edu.cn) ; Zhang, Zhuo(zhzhang@qfnu.edu.cn) |
| 英文摘要 | As an intriguing strategy for massive hydrogen production, photo electrochemical (PEC) seawater splitting compels the anode to be highly hypochlorite-resistant. Inspired by algae, we designed a robust photoelectrocatalyst that WO3 nanorods (NRs) are covered by N/W co-doped (Co, Ni, W)OxNy nanosheets (NSs). The NSs expose (111) faces and are decorated by (Co, Ni)WO4 nanoparticles. DFT calculations reveal that Co and Ni atoms on the (111) surface of N/W co-doped NSs are more likely to adsorb OH-, while W atoms are more favorable to adsorb Cl-. Secondly, the lattice distortion and multi-crystal phases of NSs are triggered by doped W atoms, and the evacuation of 5d electrons makes W atoms as donor centers, leading to enhanced catalytic activity of CoNi atoms and corrosion resistance to Cl-. Furthermore, the N atoms expand the valence band of CoNiOx and elevate the conduction band of (Co, Ni)WO4, facilitating more electrons to participate in PEC reaction and the realization of seawater full-splitting. Resultantly, the N/W co-doped (Co, Ni, W)OxNy/WO3 hetero-NRs (HNRs) demonstrate a PEC current density about 0.35 mA/cm(2) at 1.23 VRHE with durability over 100 hours in seawater. This work provides a practical strategy towards the durable PEC anode for seawater splitting. |
| WOS关键词 | DOUBLE HYDROXIDE NANOSHEETS ; CAULERPA-TAXIFOLIA ; CHARGE SEPARATION ; NANOWIRE ARRAYS ; WATER ; REDUCTION ; ELECTROCATALYST ; PHOTOANODES ; CATALYSTS |
| 资助项目 | Natural Science Foundation of Shandong Province[ZR2020MA065] ; National Nat-ural Science Foundation of China[52102324] ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund[YZJJZX202018] ; Hefei National Laboratory for Physical Sciences at the Microscale[KF2020109] |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001316760500001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Natural Science Foundation of Shandong Province ; National Nat-ural Science Foundation of China ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund ; Hefei National Laboratory for Physical Sciences at the Microscale |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/135476]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Chen, Bin; Yu, Xiujun; Zhang, Zhuo |
| 作者单位 | 1.Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China 2.Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China 3.Chinese Acad Sci, Key Lab Mat Phys, Hefei 230031, Peoples R China 4.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, HFIPS, Hefei 230031, Peoples R China 5.Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Guangcai,Li, Wenbin,Wang, Fei,et al. Biomimetic (Co, Ni, W)OxNy/WO3 x N y /WO3 photoelectrocatalyst for robust seawater oxidation[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2024,1007. |
| APA | Ma, Guangcai.,Li, Wenbin.,Wang, Fei.,Zhang, Lunyong.,Chen, Bin.,...&Zhang, Zhuo.(2024).Biomimetic (Co, Ni, W)OxNy/WO3 x N y /WO3 photoelectrocatalyst for robust seawater oxidation.JOURNAL OF ALLOYS AND COMPOUNDS,1007. |
| MLA | Ma, Guangcai,et al."Biomimetic (Co, Ni, W)OxNy/WO3 x N y /WO3 photoelectrocatalyst for robust seawater oxidation".JOURNAL OF ALLOYS AND COMPOUNDS 1007(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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