The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau
文献类型：期刊论文
| 作者 | Liu, Yuliang4,5; Nie, Wei4,5; Qi, Ximeng4,5; Li, Yuanyuan4,5; Xu, Tao4,5; Liu, Chong4,5; Ge, Dafeng4,5; Chen, Liangduo4,5; Niu, Guangdong4,5; Wang, Jinbo4,5 |
| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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| 出版日期 | 2024-09-26 |
| 关键词 | new particle formation highly oxygenated organic molecules Qinghai-Tibet Plateau sesquiterpenes diterpenes NOx-influenced chemistry biogenic-anthropogenic interactions |
| ISSN号 | 0013-936X |
| DOI | 10.1021/acs.est.4c04112 |
| 通讯作者 | Nie, Wei(niewei@nju.edu.cn) |
| 英文摘要 | Aerosol particles originating from the Qinghai-Tibet Plateau (QTP) readily reach the free troposphere, potentially affecting global radiation and climate. Although new particle formation (NPF) is frequently observed at such high altitudes, its precursors and their underlying chemistry remain poorly understood. This study presents direct observational evidence of anthropogenic influences on biogenic NPF on the southeastern QTP, near the Himalayas. The mean particle nucleation rate (J(1.7)) is 2.6 cm(-3) s(-1), exceeding the kinetic limit of sulfuric acid (SA) nucleation (mean SA: 2.4 x 10(5) cm(-3)). NPF is predominantly driven by highly oxygenated organic molecules (HOMs), possibly facilitated by low SA levels. We identified 1538 ultralow-volatility HOMs driving particle nucleation and 764 extremely low-volatility HOMs powering initial particle growth, with mean total concentrations of 1.5 x 10(6) and 3.7 x 10(6) cm(-3), respectively. These HOMs are formed by atmospheric oxidation of biogenic precursors, unexpectedly including sesquiterpenes and diterpenes alongside the commonly recognized monoterpenes. Counterintuitively, over half of HOMs are organic nitrates, mainly produced by interacting with anthropogenic NOx via RO2+NO terminations or NO3-initiated oxidations. These findings advance our understanding of NPF mechanisms in this climate-sensitive region and underscore the importance of heavy terpene and NOx-influenced chemistry in assessing anthropogenic-biogenic interactions with climate feedbacks. |
| WOS关键词 | SULFURIC-ACID ; OXIDATION-PRODUCTS ; ORGANIC-COMPOUNDS ; M A.S.L. ; NUCLEATION ; INSIGHTS ; GROWTH |
| 资助项目 | Second Tibetan Plateau Scientific Expedition and Research (STEP) program[2019QZKK0106] ; National Natural Science Foundation of China (NSFC) project[42220104006] ; National Natural Science Foundation of China (NSFC) project[42075101] ; National Natural Science Foundation of China (NSFC) project[42305119] ; Jiangsu Provincial Collaborative Innovation Center of Climate Change ; Fundamental Research Funds for the Central Universities |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001324876500001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Second Tibetan Plateau Scientific Expedition and Research (STEP) program ; National Natural Science Foundation of China (NSFC) project ; Jiangsu Provincial Collaborative Innovation Center of Climate Change ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/135592]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Nie, Wei |
| 作者单位 | 1.Peking Univ, Coll Environm Sci & Engn, State Key Joint Lab Environm Simulat & Pollut Cont, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, Ctr Excellence Quaternary Sci & Global Change, State Key Lab Loess Sci, Xian 710061, Peoples R China 3.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, HFIPS, Hefei 230031, Peoples R China 4.Nanjing Univ, Sch Atmospher Sci, Joint Int Res Lab Atmospher & Earth Syst Res, Nanjing 210023, Peoples R China 5.Natl Observat & Res Stn Atmospher Proc & Environm, Nanjing 210023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yuliang,Nie, Wei,Qi, Ximeng,et al. The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2024. |
| APA | Liu, Yuliang.,Nie, Wei.,Qi, Ximeng.,Li, Yuanyuan.,Xu, Tao.,...&Ding, Aijun.(2024).The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau.ENVIRONMENTAL SCIENCE & TECHNOLOGY. |
| MLA | Liu, Yuliang,et al."The Pivotal Role of Heavy Terpenes and Anthropogenic Interactions in New Particle Formation on the Southeastern Qinghai-Tibet Plateau".ENVIRONMENTAL SCIENCE & TECHNOLOGY (2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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