Heterostructure-anchored 3D CNT-bridged graphene architecture via layer-by-layer structural engineering for thick electrodes of supercapacitors
文献类型：期刊论文
| 作者 | Song, Yanping2,3,4; Li, Nian2,4 ; Kang, Jun2,4; Li, Zhao2,3,4; Hong, Na2,3,4; Han, Shuai1; Chen, Liqing2,3,4; Zhang, Shudong2,4; Liu, Cui2,4; Song, Congfa5
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| 刊名 | CHEMICAL ENGINEERING JOURNAL
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| 出版日期 | 2024-10-01 |
| 卷号 | 497 |
| 关键词 | Laser-induced graphene Layer by layer Heterostructure Thick electrode Supercapacitor |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2024.154557 |
| 通讯作者 | Li, Nian(linian@issp.ac.cn) ; Wang, Zhenyang(zywang@iim.ac.cn) |
| 英文摘要 | The emerging thick electrode concept is dedicated to maximize active material areal loading at the device-scale through straightforward structural designs to meet the high energy density demand. Nevertheless, overcoming the sluggish charge kinetics and complex manufacturing route in thick composite electrodes is still challenging. Herein, a novel all-laser structural engineering protocol is developed to construct MnO-Mn3O4/MnS heterostructure-anchored 3D porous graphene architecture with reinforced carbon nanotube (CNT) interface (MHGC) by layer-by-layer laser induction of polyethersulfone film containing manganese acetate precursors without introducing any templates or catalysts. Creatively, along with the synchronous generation of porous graphene and multivalent manganese compounds heterostructures, a uniform distribution process of nanoparticles is integrated into a one-step in-situ laser irradiation, which is unique and straightforward for preparing thick composite electrodes. Besides, the interlayer bridging of CNT network between MnO-Mn3O4/MnS/graphene layers accelerates electron transport, accompanied by the ameliorative deep diffusion of ions by open graphene macropores derived from laser-assisted vaporization. Thanks to the configuration of efficient electronic bridge and ion channel, combined with multi-heterointerface and fast surface reaction kinetics endowed by heterostructure nanoparticles, MHGC electrode with a thickness of 442 mu m delivers a high specific capacitance of 954.5 mF cm- 2 (at 0.5 mA cm- 2). The assembled symmetrical supercapacitor with LiCl aqueous electrolyte exhibits a broadened potential window of 1.3 V, obtaining a prominent energy density (39.99 mu Wh cm- 2) and power density (1625 mu W cm- 2). This advanced laser engineering and enabled thick electrodes open a brand-new avenue in burgeoning energy chemistries, not limited to supercapacitors and rechargeable batteries. |
| WOS关键词 | MNO2 |
| 资助项目 | National Key Research and Development Project[2020YFA0210703] ; National Key Research and Development Project[2022YFA1203604] ; National Natural Science Foundation of China[52171053] ; National Natural Science Foundation of China[12204488] ; Major Scientific and Technological Special Project of Anhui Province[202103a05020013] ; CAS Project for Young Scientists in Basic Research[YSBR-070] ; Natural Science Foundation of Anhui Province[2208085ME109] ; HFIPS Director's Fund[YZJJ-GGZX-2022-01] ; HFIPS Director's Fund[GGZX-GTCX-2023-01] ; Science Research Project of Hebei Education Department[QN2024232] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001291724000001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Key Research and Development Project ; National Natural Science Foundation of China ; Major Scientific and Technological Special Project of Anhui Province ; CAS Project for Young Scientists in Basic Research ; Natural Science Foundation of Anhui Province ; HFIPS Director's Fund ; Science Research Project of Hebei Education Department |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/135967]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Li, Nian; Wang, Zhenyang |
| 作者单位 | 1.Hebei Univ Engn, Sch Math & Phys, Handan 056038, Hebei, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China 3.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 4.Chinese Acad Sci, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Hefei 230031, Anhui, Peoples R China 5.Anhui Gelanke New Mat Technol Co LTD, Hefei 230088, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Yanping,Li, Nian,Kang, Jun,et al. Heterostructure-anchored 3D CNT-bridged graphene architecture via layer-by-layer structural engineering for thick electrodes of supercapacitors[J]. CHEMICAL ENGINEERING JOURNAL,2024,497. |
| APA | Song, Yanping.,Li, Nian.,Kang, Jun.,Li, Zhao.,Hong, Na.,...&Wang, Zhenyang.(2024).Heterostructure-anchored 3D CNT-bridged graphene architecture via layer-by-layer structural engineering for thick electrodes of supercapacitors.CHEMICAL ENGINEERING JOURNAL,497. |
| MLA | Song, Yanping,et al."Heterostructure-anchored 3D CNT-bridged graphene architecture via layer-by-layer structural engineering for thick electrodes of supercapacitors".CHEMICAL ENGINEERING JOURNAL 497(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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