A general strategy for synthesizing bimetallic Pt-based nanoclusters supported on carbon black via non-thermal plasma
文献类型：期刊论文
| 作者 | Sun, Hongmei2; Liu, Chang2; Yu, Nan1; Ni, Guohua2; Xia, Jing3 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2024-09-19 |
| 卷号 | 83 |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2024.08.135 |
| 通讯作者 | Ni, Guohua(ghni@ipp.ac.cn) ; Xia, Jing(xiajing@mail.ipc.ac.cn) |
| 英文摘要 | Downsizing Pt-based catalysts to generate a higher surface-to-volume ratio and maximize atom utilization efficiency has been recognized as an effective strategy to achieve high mass activity. However, the synthesis of homogeneous, ultra-small bimetallic nanoclusters remains a significant challenge due to the difficulties in controlling stoichiometry and surface state control, large miscible gaps between different metals and surface state changes induced by the reaction gas environment. In this paper, bimetallic Pt-based nanoclusters such as PtPd, PtRu, PtCu deposited on carbon black (Vulcan XC72R) were fabricated by the reduction of H2 2 plasma.The structure and morphology of those prepared catalysts were revealed by HAADF-STEM, HR-TEM, EDS and XPS. The results indicated the prepared Pt-based nano- clusters displayed high dispersibility and small size owning to the non-equilibrium characteristics of non-thermal plasma (NTPs). The average sizes of PtPd, PtRu and PtCu were 2.06 +/- 0.68 nm, 3.66 +/- 1.34 nm and 1.98 +/- 0.7 nm, respectively. Meanwhile, the synthesized PtPd nanoclusters with the ratio of 3:4 exhibited high catalytic activity in the hydrogen evolution reaction (HER). The Pt3Pd4/VR-P 3 Pd 4 /VR-P displayed a low overpotential (19 mV) at 10 mA/cm2 2 and achieved a high mass activity of 5.4 A/mg for HER in 0.5 M H2SO4 2 SO 4 solution, which was 13.8 times higher than those of the commercial Pt/C catalysts. Moreover, the Pt3Pd4/VR-P 3 Pd 4 /VR-P demonstrated excellent stability with a negatively shifting about 40 mV after 10,000 cycles at a current density of 10 mA/cm2, 2 , which was close to that of JM-Pt/C (32 mV). The results prove NTPs technology is effective for the preparation of bimetallic Pt-based nanoclusters. |
| WOS关键词 | METHANOL OXIDATION PERFORMANCE ; HYDROGEN EVOLUTION REACTION ; OXYGEN REDUCTION ; ACTIVATED CARBON ; VULCAN XC72R ; CATALYSTS ; PLATINUM ; ENHANCE ; NANOTUBES ; ALLOY |
| 资助项目 | National Natural Science Foundation of China (NSFC)[12105325] ; National Natural Science Foundation of China (NSFC)[11875295] ; National Natural Science Foundation of China (NSFC)[12275317] ; University Synergy Innovation Program of Anhui Province[GXXT-2021-013] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:001294752700001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China (NSFC) ; University Synergy Innovation Program of Anhui Province |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/136049]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Ni, Guohua; Xia, Jing |
| 作者单位 | 1.Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241002, Peoples R China 2.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Plasma Phys, Hefei 230031, Peoples R China 3.Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Hongmei,Liu, Chang,Yu, Nan,et al. A general strategy for synthesizing bimetallic Pt-based nanoclusters supported on carbon black via non-thermal plasma[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2024,83. |
| APA | Sun, Hongmei,Liu, Chang,Yu, Nan,Ni, Guohua,&Xia, Jing.(2024).A general strategy for synthesizing bimetallic Pt-based nanoclusters supported on carbon black via non-thermal plasma.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,83. |
| MLA | Sun, Hongmei,et al."A general strategy for synthesizing bimetallic Pt-based nanoclusters supported on carbon black via non-thermal plasma".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 83(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。