100% selective methane conversion to C1 products over Ni/CeO2 nanorods
文献类型：期刊论文
| 作者 | Cui, Yufei4; Yang, Hui4; Zhou, Wenhao4; Ma, Yongqing4; Zheng, Ganhong4; Chen, Bin2,3,5 ; Zhu, Chuhong4; Wang, Meiling1,4
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| 刊名 | JOURNAL OF CATALYSIS
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| 出版日期 | 2024-07-01 |
| 卷号 | 435 |
| 关键词 | Photocatalysis CH4 conversion Ni/CeO2 nanorods C1 products |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2024.115546 |
| 通讯作者 | Chen, Bin(bchen@issp.ac.cn) ; Wang, Meiling(mlw@ahu.edu.cn) |
| 英文摘要 | Selective CH4 upgrading to C1 products and avoiding over oxidation remains a key challenge. Here, we develop a highly efficient Ni/CeO2 nanorods containing both uniformly dispersed Ni-single-site and NiOx/CeO2 heterojunction for 100 % selectively CH4 conversion to C1 products (CH3OH, HCHO, CH3OOH and HCOOH). Under optimized photocatalytic experimental conditions, a high C1 product yield of 5.6 mmol g(-1)h(-1) was obtained with 100 % selectivity with presence of H2O2. Mechanism study showed that the Ni-single-site together with formed oxygen vacancy (O-v) facilitated CH4 adsorption and activation. The terminal O atom of adsorbed (OOH)-O-center dot can fill the O-v, with the remaining *OH initiating *CH3 dehydrogenation and forming *CH2OH, which further reacts with *OH to generate the main product HCHO. During the whole photocatalytic process, the formed NiOx/CeO2 heterojunction promoted carrier separation and enhanced catalytic performance. |
| WOS关键词 | SOLID-SOLUTIONS ; CEO2 ; PHOTOOXIDATION ; OXIDATION ; OXYGEN |
| 资助项目 | Natural Science Foundation of Education Department of Anhui Province -key project[2023AH050112] ; National Natural Science Foundation of China[52102324] ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund[BJPY2023B04] ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund[YZJJ-GGZX-2022-01] ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund[YZJJZX202018] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001243429400001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Natural Science Foundation of Education Department of Anhui Province -key project ; National Natural Science Foundation of China ; Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/136200]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Chen, Bin; Wang, Meiling |
| 作者单位 | 1.Anhui Univ, Sch Mat Sci & Engn, Hefei 230039, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, HFIPS, Hefei 230031, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, HFIPS, Hefei 230031, Peoples R China 4.Anhui Univ, Sch Mat Sci & Engn, Hefei 230601, Peoples R China 5.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Yufei,Yang, Hui,Zhou, Wenhao,et al. 100% selective methane conversion to C1 products over Ni/CeO2 nanorods[J]. JOURNAL OF CATALYSIS,2024,435. |
| APA | Cui, Yufei.,Yang, Hui.,Zhou, Wenhao.,Ma, Yongqing.,Zheng, Ganhong.,...&Wang, Meiling.(2024).100% selective methane conversion to C1 products over Ni/CeO2 nanorods.JOURNAL OF CATALYSIS,435. |
| MLA | Cui, Yufei,et al."100% selective methane conversion to C1 products over Ni/CeO2 nanorods".JOURNAL OF CATALYSIS 435(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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