中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries

文献类型:期刊论文

作者Xu, Hai Yan1,2,3; Fei, Guang Tao2,3; Xu, Shao Hui2,3; Chen, Wen Chao1,2,3; Li, Shi Jia1,2,3; Li, Xin Feng4; Ouyang, Hao Miao4
刊名SOLID STATE IONICS
出版日期2024-09-01
卷号412
关键词Separator Solid electrolyte SiO2 Solid electrolyte interphase Interfacial impedance
ISSN号0167-2738
DOI10.1016/j.ssi.2024.116603
通讯作者Fei, Guang Tao(gtfei@issp.ac.cn) ; Xu, Shao Hui(shxu@issp.ac.cn)
英文摘要The separator is crucial to the performance and safety of the battery. This study prepared a polypropylene (PP) /solid electrolyte Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) /SiO 2 composite separator (PP/LATP/SiO 2 ). The experimental results demonstrate significant enhancements in the electrolyte wettability and thermal stability of the separator. Furthermore, the lithium-ion transference number ( t + ) has been raised from 0.22 to 0.56. In electrochemical performance tests, the lithium symmetric battery assembled with the PP/LATP/SiO 2 composite separator exhibits an exceptionally long cycle life, sustaining stable cycling for 900 h at a current density of 0.5 mA cm -2 . This composite separator, combining the solid electrolyte and SiO 2 layer, effectively facilitates lithium-ion transport and reduces the occurrence of electrode side reactions, thereby enhancing the performance and safety of the battery.
WOS关键词METAL ANODE ; COMPOSITE SEPARATOR ; LIQUID ELECTROLYTE ; IONIC-CONDUCTIVITY ; THERMAL-STABILITY ; STATE ELECTROLYTE ; INTERPHASE ; PERFORMANCES
资助项目Anhui Pro- vincial Major Science and Technology Project, P. R. China[202203a07020026] ; National Natural Science Foundation of China[51971210] ; Anhui Provincial Natural Science Foundation, P. R. China[2208085ME112]
WOS研究方向Chemistry ; Physics
语种英语
WOS记录号WOS:001248470000001
出版者ELSEVIER
资助机构Anhui Pro- vincial Major Science and Technology Project, P. R. China ; National Natural Science Foundation of China ; Anhui Provincial Natural Science Foundation, P. R. China
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/136430]  
专题中国科学院合肥物质科学研究院
通讯作者Fei, Guang Tao; Xu, Shao Hui
作者单位1.Univ Sci & Technol China, Hefei 230026, Peoples R China
2.Chinese Acad Sci, Key Lab Mat Phys, Inst Solid State Phys, Hefei Inst Phys Sci, POB 1129, Hefei 230031, Peoples R China
3.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Anhui Key Lab Nanomat & Nanotechnol, POB 1129, Hefei 230031, Peoples R China
4.Hefei Got High Tech Power Energy Co Ltd, Hefei 230012, Peoples R China
推荐引用方式
GB/T 7714
Xu, Hai Yan,Fei, Guang Tao,Xu, Shao Hui,et al. Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries[J]. SOLID STATE IONICS,2024,412.
APA Xu, Hai Yan.,Fei, Guang Tao.,Xu, Shao Hui.,Chen, Wen Chao.,Li, Shi Jia.,...&Ouyang, Hao Miao.(2024).Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries.SOLID STATE IONICS,412.
MLA Xu, Hai Yan,et al."Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries".SOLID STATE IONICS 412(2024).

入库方式: OAI收割

来源:合肥物质科学研究院

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