Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries
文献类型:期刊论文
作者 | Xu, Hai Yan1,2,3; Fei, Guang Tao2,3![]() |
刊名 | SOLID STATE IONICS
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出版日期 | 2024-09-01 |
卷号 | 412 |
关键词 | Separator Solid electrolyte SiO2 Solid electrolyte interphase Interfacial impedance |
ISSN号 | 0167-2738 |
DOI | 10.1016/j.ssi.2024.116603 |
通讯作者 | Fei, Guang Tao(gtfei@issp.ac.cn) ; Xu, Shao Hui(shxu@issp.ac.cn) |
英文摘要 | The separator is crucial to the performance and safety of the battery. This study prepared a polypropylene (PP) /solid electrolyte Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) /SiO 2 composite separator (PP/LATP/SiO 2 ). The experimental results demonstrate significant enhancements in the electrolyte wettability and thermal stability of the separator. Furthermore, the lithium-ion transference number ( t + ) has been raised from 0.22 to 0.56. In electrochemical performance tests, the lithium symmetric battery assembled with the PP/LATP/SiO 2 composite separator exhibits an exceptionally long cycle life, sustaining stable cycling for 900 h at a current density of 0.5 mA cm -2 . This composite separator, combining the solid electrolyte and SiO 2 layer, effectively facilitates lithium-ion transport and reduces the occurrence of electrode side reactions, thereby enhancing the performance and safety of the battery. |
WOS关键词 | METAL ANODE ; COMPOSITE SEPARATOR ; LIQUID ELECTROLYTE ; IONIC-CONDUCTIVITY ; THERMAL-STABILITY ; STATE ELECTROLYTE ; INTERPHASE ; PERFORMANCES |
资助项目 | Anhui Pro- vincial Major Science and Technology Project, P. R. China[202203a07020026] ; National Natural Science Foundation of China[51971210] ; Anhui Provincial Natural Science Foundation, P. R. China[2208085ME112] |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
WOS记录号 | WOS:001248470000001 |
出版者 | ELSEVIER |
资助机构 | Anhui Pro- vincial Major Science and Technology Project, P. R. China ; National Natural Science Foundation of China ; Anhui Provincial Natural Science Foundation, P. R. China |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/136430] ![]() |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Fei, Guang Tao; Xu, Shao Hui |
作者单位 | 1.Univ Sci & Technol China, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Key Lab Mat Phys, Inst Solid State Phys, Hefei Inst Phys Sci, POB 1129, Hefei 230031, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Anhui Key Lab Nanomat & Nanotechnol, POB 1129, Hefei 230031, Peoples R China 4.Hefei Got High Tech Power Energy Co Ltd, Hefei 230012, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Hai Yan,Fei, Guang Tao,Xu, Shao Hui,et al. Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries[J]. SOLID STATE IONICS,2024,412. |
APA | Xu, Hai Yan.,Fei, Guang Tao.,Xu, Shao Hui.,Chen, Wen Chao.,Li, Shi Jia.,...&Ouyang, Hao Miao.(2024).Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries.SOLID STATE IONICS,412. |
MLA | Xu, Hai Yan,et al."Functional modification of polypropylene separators with solid electrolyte LATP and SiO 2 coatings for lithium batteries".SOLID STATE IONICS 412(2024). |
入库方式: OAI收割
来源:合肥物质科学研究院
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