Plasma-induced, N-doped, and reduced graphene oxide-incorporated NiCo-layered double hydroxide nanowires as a high-capacity redox mediator for sustainable decoupled water electrolysis
文献类型：期刊论文
| 作者 | He, Yuan2,3; Xiang, Ting1; Ren, Xuemei2 ; Fang, Shidong2; Chen, Changlun2,4
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| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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| 出版日期 | 2024-11-15 |
| 卷号 | 674 |
| 关键词 | Hydrogen production Decoupled water electrolysis Redox mediator Nonthermal plasma |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2024.06.135 |
| 通讯作者 | Fang, Shidong(fangsd@ipp.ac.cn) ; Chen, Changlun(clchen@ipp.ac.cn) |
| 英文摘要 | Although the recent emergence of decoupled water electrolysis prevents typical H2/O2 mixing, the further development of decoupled water electrolysis has been confined by the lack of reliable redox mediator (RM) electrodes to support sustainable H2 production. As energy storage electrodes, layered double hydroxides (LDHs) possess inherently poor conductivity/stability, which can be improved by growing LDHs on graphene substrates in situ. The proper modification of the graphene surface structure can improve the electron transport and energy storage capacity of composite electrodes, while current methods are usually cumbersome and require high temperatures/chemical reagents. Therefore, in this study, dip coating was adopted to grow graphene oxide (GO) on nickel foam (NF). Then, the GO was reduced using nonthermal plasma (NTP) to reduced GO (rGO) in situ while simultaneously implementing N doping to obtain plasma-assisted N-doped rGO on NF (PNrGO/NF). The uniform conductive substrate ensured the subsequent growth of less-aggregated NiCo-LDH nanowires, which improved the conductivity and energy storage capacity (5.93 C/cm2 at 5 mA/cm2) of the NiCo-LDH@PNrGO/NF. For the decoupled system, the composite RM electrode exhibited a high buffering capacity for 1300 s during the decoupled H2/O2 evolution, and in the conventional coupled system, the necessary input voltage of 1.67 V was separated into two lower ones, 1.42/0.33 V for H 2 /O 2 evolutions, respectively. Simultaneously, the RM possessed outstanding redox reversibility and structural stability during long-term cycling. This work could offer a feasible strategy for using NTP to synthesize excellent RM electrodes for application to decoupled water electrolysis. |
| WOS关键词 | HETEROSTRUCTURE ; NANOSHEETS ; REDUCTION ; COMPOSITE ; EVOLUTION ; NITROGEN ; FILMS |
| 资助项目 | National Natural Science Foundation of China[12027813] ; Institute of Energy, Hefei Comprehensive National Science Center (Anhui Energy Laboratory) China[GXXT-2022- 27] ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; High Magnetic Field Laboratory of Anhui Province |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001259750500001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Natural Science Foundation of China ; Institute of Energy, Hefei Comprehensive National Science Center (Anhui Energy Laboratory) China ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; High Magnetic Field Laboratory of Anhui Province |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/136732]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Fang, Shidong; Chen, Changlun |
| 作者单位 | 1.Hefei Comprehens Natl Sci Ctr, Inst Energy, Anhui Energy Lab, Hefei 230023, Peoples R China 2.Chinese Acad Sci, Inst Plasma Phys, HFIPS, POB 1126, Hefei 230031, Peoples R China 3.Univ Sci & Technol China, Hefei 230026, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med, Jiangsu Higher Educ Inst, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Yuan,Xiang, Ting,Ren, Xuemei,et al. Plasma-induced, N-doped, and reduced graphene oxide-incorporated NiCo-layered double hydroxide nanowires as a high-capacity redox mediator for sustainable decoupled water electrolysis[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2024,674. |
| APA | He, Yuan,Xiang, Ting,Ren, Xuemei,Fang, Shidong,&Chen, Changlun.(2024).Plasma-induced, N-doped, and reduced graphene oxide-incorporated NiCo-layered double hydroxide nanowires as a high-capacity redox mediator for sustainable decoupled water electrolysis.JOURNAL OF COLLOID AND INTERFACE SCIENCE,674. |
| MLA | He, Yuan,et al."Plasma-induced, N-doped, and reduced graphene oxide-incorporated NiCo-layered double hydroxide nanowires as a high-capacity redox mediator for sustainable decoupled water electrolysis".JOURNAL OF COLLOID AND INTERFACE SCIENCE 674(2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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