A Strained Donor-Acceptor Carbon Nanohoop: Synthesis, Photophysical and Charge Transport Properties
文献类型：期刊论文
| 作者 | Fang, Pengwei1; Cheng, Zaitian3; Peng, Wei1; Xu, Jixian1; Zhang, Xinyu1; Zhang, Fapei3 ; Zhuang, Guilin2; Du, Pingwu1
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| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2024-07-04 |
| 关键词 | donor-acceptor system cycloparaphenylenes solvatofluorochromism charge transport |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202407078 |
| 通讯作者 | Zhang, Fapei(fzhang@hmfl.ac.cn) ; Zhuang, Guilin(glzhuang@ahnu.edu.cn) ; Du, Pingwu(dupingwu@ustc.edu.cn) |
| 英文摘要 | Herein, we report the synthesis of a novel intramolecular donor-acceptor (D-A) system ([12]CPP-8TPAOMe) based on cycloparaphenylenes (CPPs) grafted with eight di(4-methoxyphenyl)amino groups (TPAOMe) as donors. Compared to [12]CPP, D-A nanohoop exhibited significant changes in physical properties, including a large redshift (>78 nm) in the fluorescence spectrum and novel positive solvatofluorochromic properties with a maximum peak ranging from 484 nm to 546 nm. The potential applications of [12]CPP-8TPAOMe in electron- and hole-transport devices were further investigated, and its bipolar behavior as a charge transport active layer was clearly observed. |
| WOS关键词 | ELECTRON-TRANSFER ; FLUORESCENCE-SPECTRA ; RATIONAL DESIGN ; CYCLOPARAPHENYLENES ; POLYTHIOPHENE ; MACROCYCLES ; ABSORPTION ; COMPLEXES ; DYADS ; DIMER |
| 资助项目 | National Natural Science Foundation of China[22225108] ; National Natural Science Foundation of China[21971229] ; National Natural Science Foundation of China[22072135] ; Hefei National Research Center for Physical Sciences at the Microscale |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001262696300001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Hefei National Research Center for Physical Sciences at the Microscale |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/136777]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zhang, Fapei; Zhuang, Guilin; Du, Pingwu |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Dept Mat Sci & Engn, Key Lab Precis & Intelligent Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China 2.Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Minist Educ, Wuhu 241002, Anhui, Peoples R China 3.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme C, High Magnet Field Lab, HFIPS, 96 Jinzhai Rd, Hefei 230031, Anhu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Pengwei,Cheng, Zaitian,Peng, Wei,et al. A Strained Donor-Acceptor Carbon Nanohoop: Synthesis, Photophysical and Charge Transport Properties[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024. |
| APA | Fang, Pengwei.,Cheng, Zaitian.,Peng, Wei.,Xu, Jixian.,Zhang, Xinyu.,...&Du, Pingwu.(2024).A Strained Donor-Acceptor Carbon Nanohoop: Synthesis, Photophysical and Charge Transport Properties.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
| MLA | Fang, Pengwei,et al."A Strained Donor-Acceptor Carbon Nanohoop: Synthesis, Photophysical and Charge Transport Properties".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024). |
入库方式： OAI收割
来源：合肥物质科学研究院
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