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Modulating the Electrolyte Microenvironment in Electrical Double Layer for Boosting Electrocatalytic Nitrate Reduction to Ammonia

文献类型：期刊论文

作者Wen, Weidong1; Fang, Shidong2,3; Zhou, Yitong5; Zhao, Ying4; Li, Peng1; Yu, Xin-Yao1
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2024-07-02
关键词nitrate reduction reaction kinetics proton transport alkali metal cation electrical double layer
ISSN号1433-7851
DOI10.1002/anie.202408382
通讯作者Zhou, Yitong(zhouyt@ahu.edu.cn) ; Li, Peng(yuxinyao@ahu.edu.cn) ; Yu, Xin-Yao(peng-li@ahu.edu.cn)
英文摘要Electrochemical nitrate reduction reaction (NO3RR) is a promising approach to achieve remediation of nitrate-polluted wastewater and sustainable production of ammonia. However, it is still restricted by the low activity, selectivity and Faraday efficiency for ammonia synthesis. Herein, we propose an effective strategy to modulate the electrolyte microenvironment in electrical double layer (EDL) by mediating alkali metal cations in the electrolyte to enhance the NO3RR performance. Taking bulk Cu as a model catalyst, the experimental study reveals that the NO3--to-NH3 performance in different electrolytes follows the trend Li+
WOS关键词CO2 ELECTROREDUCTION ; INTERFACE ; DESIGN
资助项目University Synergy Innovation Program of Anhui Province[GXXT-2022-026] ; Project of Anhui Provincial Department of Education[2022AH050112] ; Project of Anhui Provincial Department of Education[2022AH010004] ; Natural Science Research Project of Universities in Anhui Province[KJ2021A0070] ; Natural Science Research Project of Universities in Anhui Province[KJ2021A1168]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:001259681200001
出版者WILEY-V C H VERLAG GMBH
资助机构University Synergy Innovation Program of Anhui Province ; Project of Anhui Provincial Department of Education ; Natural Science Research Project of Universities in Anhui Province
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/136780]  
专题中国科学院合肥物质科学研究院
通讯作者Zhou, Yitong; Li, Peng; Yu, Xin-Yao
作者单位1.Anhui Univ, Sch Mat Sci & Engn, Hefei 230601, Peoples R China
2.Hefei Comprehens Natl Sci Ctr, Inst Energy, Anhui Energy Lab, Hefei 230051, Peoples R China
3.Chinese Acad Sci, Hefei Inst Phys Sci, Hefei 230031, Peoples R China
4.Anhui Xinhua Univ, Sch Pharm, Hefei 230088, Peoples R China
5.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Peoples R China
推荐引用方式
GB/T 7714		 Wen, Weidong,Fang, Shidong,Zhou, Yitong,et al. Modulating the Electrolyte Microenvironment in Electrical Double Layer for Boosting Electrocatalytic Nitrate Reduction to Ammonia[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024.
APA Wen, Weidong,Fang, Shidong,Zhou, Yitong,Zhao, Ying,Li, Peng,&Yu, Xin-Yao.(2024).Modulating the Electrolyte Microenvironment in Electrical Double Layer for Boosting Electrocatalytic Nitrate Reduction to Ammonia.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA Wen, Weidong,et al."Modulating the Electrolyte Microenvironment in Electrical Double Layer for Boosting Electrocatalytic Nitrate Reduction to Ammonia".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024).

入库方式： OAI收割

来源：合肥物质科学研究院

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