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High Density 3D Carbon Tube Nanoarray Electrode Boosting the Capacitance of Filter Capacitor

文献类型：期刊论文

作者Chen, Gan1,2,5; Han, Fangming1,2,5; Ma, Huachun4; Li, Pei1,2,5; Zhou, Ziyan1,2,5; Wang, Pengxiang1,2,5; Li, Xiaoyan4; Meng, Guowen1,2,5; Wei, Bingqing3
刊名NANO-MICRO LETTERS
出版日期2024-12-01
卷号16
关键词Compactly arranged Three-dimensional carbon tube nanoarray Dimensional carbon tube nanoarray Fast frequency response Electric double-layer capacitors Layer capacitors AC line-filtering Filtering
ISSN号2311-6706
DOI10.1007/s40820-024-01458-6
通讯作者Han, Fangming(fmhan@issp.ac.cn) ; Li, Xiaoyan(xiaoyanlithu@tsinghua.edu.cn) ; Meng, Guowen(gwmeng@issp.ac.cn) ; Wei, Bingqing(weib@udel.edu)
英文摘要A novel method is developed for precise control over the structure of 3D anodic aluminum oxide templates, enabling fine-tuning of both the vertical pore diameter and interspace within the templates.3D carbon tube nanoarrays featuring significantly thinner and denser tubes are constructed as high-quality electrodes for miniaturized filter capacitors.The 3D compactly arranged carbon tube-based capacitor achieves a remarkable specific areal capacitance of 3.23 mF cm-2 with a phase angle of - 80.2 degrees at 120 Hz. Electric double-layer capacitors (EDLCs) with fast frequency response are regarded as small-scale alternatives to the commercial bulky aluminum electrolytic capacitors. Creating carbon-based nanoarray electrodes with precise alignment and smooth ion channels is crucial for enhancing EDLCs' performance. However, controlling the density of macropore-dominated nanoarray electrodes poses challenges in boosting the capacitance of line-filtering EDLCs. Herein, a simple technique to finely adjust the vertical-pore diameter and inter-spacing in three-dimensional nanoporous anodic aluminum oxide (3D-AAO) template is achieved, and 3D compactly arranged carbon tube (3D-CACT) nanoarrays are created as electrodes for symmetrical EDLCs using nanoporous 3D-AAO template-assisted chemical vapor deposition of carbon. The 3D-CACT electrodes demonstrate a high surface area of 253.0 m2 g-1, a D/G band intensity ratio of 0.94, and a C/O atomic ratio of 8. As a result, the high-density 3D-CT nanoarray-based sandwich-type EDLCs demonstrate a record high specific areal capacitance of 3.23 mF cm-2 at 120 Hz and exceptional fast frequency response due to the vertically aligned and highly ordered nanoarray of closely packed CT units. The 3D-CT nanoarray electrode-based EDLCs could serve as line filters in integrated circuits, aiding power system miniaturization.
WOS关键词DOUBLE-LAYER CAPACITOR ; ELECTROCHEMICAL CAPACITORS ; ALUMINUM-OXIDE ; SUPERCAPACITORS ; PERFORMANCE ; COMPACT ; FILM
资助项目National Natural Science Foundation of China[91963202] ; National Natural Science Foundation of China[52072372] ; National Natural Science Foundation of China[52372241] ; National Natural Science Foundation of China[52232007] ; National Natural Science Foundation of China[12325203] ; HFIPS[BJPY2023A07] ; HFIPS[YZJJ-GGZX-2022-01]
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
WOS记录号WOS:001261632900001
出版者SHANGHAI JIAO TONG UNIV PRESS
资助机构National Natural Science Foundation of China ; HFIPS
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/136974]  
专题中国科学院合肥物质科学研究院
通讯作者Han, Fangming; Li, Xiaoyan; Meng, Guowen; Wei, Bingqing
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, HFIPS, Hefei 230031, Peoples R China
2.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
3.Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA
4.Tsinghua Univ, Mechanox Inst, Dept Engn Mech, Appl Mech Lab, Beijing 100084, Peoples R China
5.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, HFIPS, Hefei 230031, Peoples R China
推荐引用方式
GB/T 7714		 Chen, Gan,Han, Fangming,Ma, Huachun,et al. High Density 3D Carbon Tube Nanoarray Electrode Boosting the Capacitance of Filter Capacitor[J]. NANO-MICRO LETTERS,2024,16.
APA Chen, Gan.,Han, Fangming.,Ma, Huachun.,Li, Pei.,Zhou, Ziyan.,...&Wei, Bingqing.(2024).High Density 3D Carbon Tube Nanoarray Electrode Boosting the Capacitance of Filter Capacitor.NANO-MICRO LETTERS,16.
MLA Chen, Gan,et al."High Density 3D Carbon Tube Nanoarray Electrode Boosting the Capacitance of Filter Capacitor".NANO-MICRO LETTERS 16(2024).

入库方式： OAI收割

来源：合肥物质科学研究院

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