中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Orange-reddish emitting of trivalent samarium doped double perovskite Sr2LuNbO6 with high thermal stability for white-LED application

文献类型:期刊论文

作者Su, Wenzhi3; Ding, Shoujun1,2,3; Zhang, Chuancheng3; Wang, Miaomiao3; Ren, Hao3; Hu, Haitang3; Zou, Yong1,3; Liu, Wenpeng2
刊名JOURNAL OF LUMINESCENCE
出版日期2024-11-01
卷号275
关键词High-temperature solid-state method Double perovskite Orange-reddish phosphor White LED Sm (3+):Sr2LuNbO6
ISSN号0022-2313
DOI10.1016/j.jlumin.2024.120779
通讯作者Ding, Shoujun(sjding@ahut.edu.cn)
英文摘要A series of trivalent samarium ions (Sm3+) doped double perovskite Sr2LuNbO6 (x at% Sm3+:Sr2LuNbO6, x = 0.5-15) phosphors have been prepared via high-temperature solid-state method. The structural characterization of these phosphors was conducted employing X-ray diffraction (XRD), XRD Rietveld refinement, scanning electron microscope (SEM) and transmission electron microscope (TEM), respectively. Density functional theory calculations utilizing the Vienna ab initio simulation package (VASP) were employed to unveil the electronic structures, encompassing the band structure and density of states (DOS). Photoluminescence (PL) spectroscopy was employed to scrutinize the luminescent properties, while the thermal stability of the PL spectra was also evaluated. The most prominent emission peak, exhibiting an orange-reddish hue, was observed at 601 nm upon excitation at 406 nm. The quenching mechanism of Sm3+ ions within the Sr2LuNbO6 host lattice was identified as a dipole-dipole interaction, with the quenching concentration of 3 at%. Moreover, the phosphors demonstrated excellent thermal stability, with an activation energy (E-a) value of 0.126 eV. These findings collectively underscore the promising potential of Sm3+:Sr2LuNbO6 orange-reddish phosphors for applications in white light-emitting diodes (w-LEDs).
WOS关键词ENERGY-TRANSFER ; PHOSPHORS ; PHOTOLUMINESCENCE ; LUMINESCENCE ; BAND
资助项目National Natural Science Foundation of China[52202001] ; Major Science and Technology of Anhui Province[202203a05020002] ; University Natural Science Research Project of Anhui Province[KJ2021A0388]
WOS研究方向Optics
语种英语
WOS记录号WOS:001270260100001
出版者ELSEVIER
资助机构National Natural Science Foundation of China ; Major Science and Technology of Anhui Province ; University Natural Science Research Project of Anhui Province
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/137071]  
专题中国科学院合肥物质科学研究院
通讯作者Ding, Shoujun
作者单位1.Anhui Prov Joint Key Lab Disciplines Ind Big Data, Maanshan 243002, Anhui, Peoples R China
2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Anhui, Peoples R China
3.Anhui Univ Technol, Sch Microelect & Data Sci, Maanshan 243002, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Su, Wenzhi,Ding, Shoujun,Zhang, Chuancheng,et al. Orange-reddish emitting of trivalent samarium doped double perovskite Sr2LuNbO6 with high thermal stability for white-LED application[J]. JOURNAL OF LUMINESCENCE,2024,275.
APA Su, Wenzhi.,Ding, Shoujun.,Zhang, Chuancheng.,Wang, Miaomiao.,Ren, Hao.,...&Liu, Wenpeng.(2024).Orange-reddish emitting of trivalent samarium doped double perovskite Sr2LuNbO6 with high thermal stability for white-LED application.JOURNAL OF LUMINESCENCE,275.
MLA Su, Wenzhi,et al."Orange-reddish emitting of trivalent samarium doped double perovskite Sr2LuNbO6 with high thermal stability for white-LED application".JOURNAL OF LUMINESCENCE 275(2024).

入库方式: OAI收割

来源:合肥物质科学研究院

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