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Multiple synthesis routes for atomically precise noble metal nanoclusters

文献类型：期刊论文

作者He, Lizhong1,2; Dong, Tingting3
刊名CRYSTENGCOMM
出版日期2024-07-30
卷号26
DOI10.1039/d4ce00488d
通讯作者He, Lizhong(lzhe@xpu.edu.cn)
英文摘要Well-defined metal nanoclusters protected by thiolates, with sizes between nanocrystals and metal atoms, have attracted enormous attention due to their various structures, controllable compositions, intriguing physical and chemical properties, and potential applications. Atomically precise metal nanoclusters are a type of important nanomaterial that can provide an ideal platform to address some key challenges related to their applications. However, compared to the straightforward synthesis of larger nanoparticles, the preparation of ultra-small metal nanoclusters frequently encounters difficulties owing to the pursuit of monodispersity and atomic accuracy. Although a series of effective synthesis methods have been developed for metal nanoclusters with well-defined sizes, structures and compositions, rational design and successful preparation of atomically precise metal nanoclusters still face challenges that further hinder the enrichment of cluster libraries and the in-depth understanding of structure-property relationships. In this review, we summarize some recent advances in strategies for the synthesis of atomically precise metal nanoclusters, in particular, silver and gold nanoclusters as well as alloy nanoclusters, and emphasize the following synthesis methods including the Brust-Schiffrin method, ligand-exchange, galvanic/anti-galvanic reaction, etching, solid phase synthesis and intercluster reaction. This short review was designed to summarize the advances in synthesis methods of atomically precise metal nanoclusters.
WOS关键词LIGAND-EXCHANGE REACTIONS ; THIOLATE-PROTECTED GOLD ; ANTI-GALVANIC REDUCTION ; CORE-SIZE CONVERSION ; CRYSTAL-STRUCTURE ; SILVER NANOCLUSTERS ; ALLOY NANOCLUSTERS ; INTERCLUSTER REACTIONS ; STRUCTURE ELUCIDATION ; ELECTRONIC-PROPERTIES
资助项目National Natural Science Foundation of China[22201225] ; China Postdoctoral Science Foundation[2023M733539] ; XiangJiang Scholars Scheme Program[XJ2023006] ; Postdoctoral Researcher Scientific Activity Funding Project in Anhui Province[2023A660] ; Shaanxi Provincial Education Department[23JK0456] ; Scientific and Technological Plan Project of Xi'an Beilin District[GX2310] ; Scientific and Technological Plan Project of Xi'an Science and Technology Bureau[24GXFW0017]
WOS研究方向Chemistry ; Crystallography
语种英语
WOS记录号WOS:001271116100001
出版者ROYAL SOC CHEMISTRY
资助机构National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; XiangJiang Scholars Scheme Program ; Postdoctoral Researcher Scientific Activity Funding Project in Anhui Province ; Shaanxi Provincial Education Department ; Scientific and Technological Plan Project of Xi'an Beilin District ; Scientific and Technological Plan Project of Xi'an Science and Technology Bureau
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/137122]  
专题中国科学院合肥物质科学研究院
通讯作者He, Lizhong
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China
2.Xian Polytech Univ, Sch Mat Sci & Engn, Xian 710048, Peoples R China
3.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Shaanxi, Peoples R China
推荐引用方式
GB/T 7714		 He, Lizhong,Dong, Tingting. Multiple synthesis routes for atomically precise noble metal nanoclusters[J]. CRYSTENGCOMM,2024,26.
APA He, Lizhong,&Dong, Tingting.(2024).Multiple synthesis routes for atomically precise noble metal nanoclusters.CRYSTENGCOMM,26.
MLA He, Lizhong,et al."Multiple synthesis routes for atomically precise noble metal nanoclusters".CRYSTENGCOMM 26(2024).

入库方式： OAI收割

来源：合肥物质科学研究院

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