Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane
文献类型：期刊论文
| 作者 | Pan, Wei1,4; Deng, Yu1,4; He, Jiang-Bo1,4; Bai, Bing1; Zhu, Hua-Jie1,2,3 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2013-09-02 |
| 卷号 | 69期号:35页码:7253-7257 |
| ISSN号 | 0040-4020 |
| 关键词 | Asymmetric-axle-supported Hydrosilylation Ketimines Trichlorosilane |
| 通讯作者 | Zhu, HJ (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China. ; hjzhu@mail.-kib.ac.cn |
| 英文摘要 | A novel asymmetric-axle-supported chiral N-O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical -20 degrees C. High conversion yield and high enantioselectivity up to 96% were observed. (C) 2013 The Authors. Published by Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry, Organic |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | STEREOSELECTIVE REDUCTION ; ORGANOCATALYTIC HYDROSILYLATION ; CATALYTIC-REDUCTION ; AROMATIC KETONES ; IMINES ; DERIVATIVES ; FORMAMIDE ; ALDEHYDES ; AMINES ; ESTERS |
| 资助信息 | 973 Program [2009CB 522300]; Hebei University |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000322557500007 |
| 公开日期 | 2013-10-16 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/16663]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China 2.Hebei Univ, Key Lab Med Chem & Mol Diag, Minist Educ, Baoding 071002, Peoples R China 3.Hebei Univ, Sch Life Sci, Baoding 071002, Peoples R China 4.Grad Univ CAS, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Wei,Deng, Yu,He, Jiang-Bo,et al. Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane[J]. TETRAHEDRON,2013,69(35):7253-7257. |
| APA | Pan, Wei,Deng, Yu,He, Jiang-Bo,Bai, Bing,&Zhu, Hua-Jie.(2013).Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane.TETRAHEDRON,69(35),7253-7257. |
| MLA | Pan, Wei,et al."Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane".TETRAHEDRON 69.35(2013):7253-7257. |
入库方式： OAI收割
来源：昆明植物研究所
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