Cd mobilization in mining-impacted soils with different bedrock lithology: Insights from stable Cd isotopes
文献类型:期刊论文
作者 | Yuhui Liu; Yafei Xia; Jian-Ming Zhu; Zhengrong Wang; Chengshuai Liu; Meng Qi; Yiwen Lv; Ting Gao |
刊名 | Journal of Hazardous Materials
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出版日期 | 2024 |
卷号 | 480页码:135798 |
DOI | 10.1016/j.jhazmat.2024.135798 |
英文摘要 | The environmental risk of Cd in soils strongly depends on the mobilization of Cd in soils. However, limited knowledge exists on the redistribution of exogenic Cd inputs in soils, especially across diverse lithological regions. Herein, we aimed to investigate the fate of Cd in soils from two mining areas with contrasting lithologies (siliceous and calcareous) using stable Cd isotopes. The isotope tracing results confirm that mining activities are the main Cd source in both areas. The positive correlation between δ114/110Cd values and goethite/dolomite content indicates the release of heavy Cd isotopes during the dissolution of exogenetic minerals. Additionally, high contents of exchangeable Cd (11 % to 36 %) and Fe oxide-bound Cd (29 % to 42 %) drive plant pumps to transport heavy Cd isotopes from the deeper to upper horizons of the soils from the siliceous area. In the calcareous area, the total organic carbon content is positively correlated with the Cd concentration and δ114/110Cd value, suggesting potential complexation of Cd with organic matter due to the stabilizing effect of carbonate minerals on soil organic matter. This study highlights the different redistributions of exogenous Cd in soils from diverse lithological regions, emphasizing the need to consider regional lithology when developing soil quality standards for Cd. |
URL标识 | 查看原文 |
语种 | 英语 |
源URL | [http://ir.gyig.ac.cn/handle/42920512-1/15656] ![]() |
专题 | 地球化学研究所_环境地球化学国家重点实验室 |
作者单位 | 1.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, PR China 2.University of Chinese Academy of Sciences, Beijing 100049, PR China 3.State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, PR China 4.Department of Earth & Atmospheric Sciences, The City College of New York, CUNY, New York 10031, USA 5.Graduate Center, CUNY, New York, NY 10016, USA 6.College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, PR China 7.National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China, Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and Management, Institute of Eco-environmental and Soil Sciences, Guangdong Academy of Sciences, Guangzhou 510650, PR China |
推荐引用方式 GB/T 7714 | Yuhui Liu,Yafei Xia,Jian-Ming Zhu,et al. Cd mobilization in mining-impacted soils with different bedrock lithology: Insights from stable Cd isotopes[J]. Journal of Hazardous Materials,2024,480:135798. |
APA | Yuhui Liu.,Yafei Xia.,Jian-Ming Zhu.,Zhengrong Wang.,Chengshuai Liu.,...&Ting Gao.(2024).Cd mobilization in mining-impacted soils with different bedrock lithology: Insights from stable Cd isotopes.Journal of Hazardous Materials,480,135798. |
MLA | Yuhui Liu,et al."Cd mobilization in mining-impacted soils with different bedrock lithology: Insights from stable Cd isotopes".Journal of Hazardous Materials 480(2024):135798. |
入库方式: OAI收割
来源:地球化学研究所
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